Manufacture of Carbon Materials with High Nitrogen Content.

Nowadays one of the biggest challenges for carbon materials is their use in CO capture and their use as electrocatalysts in the oxygen reduction reaction (ORR). In both cases, it is necessary to dope the carbon with nitrogen species. Conventional methods to prepare nitrogen doped carbons such as melamine carbonization or NH treatment generate nitrogen doped carbons with insufficient nitrogen content. In the present research, a series of activated carbons derived from MOFs (ZIF-8, ZIF-67) are presented. Activated carbons have been prepared in a single step, by pyrolysis of the MOF in an inert atmosphere, between 600 and 1000 °C. The carbons have a nitrogen content up to 20 at.% and a surface area up to 1000 m/g. The presence of this nitrogen as pyridine or pyrrolic groups, and as quaternary nitrogen are responsible for the great adsorption capacity of CO, especially the first two. The presence of Zn and Co generates very different carbonaceous structures. Zn generates a greater porosity development, which makes the doped carbons ideal for CO capture. Co generates more graphitized doped carbons, which make them suitable for their use in electrochemistry.