Ke Jiangang, Xie Zhuoming, Liu Rui, Jing Ke, Cheng Xiang, Wang Hui, Wang Xianping, Wu Xuebang, Fang Qianfeng, Liu Changsong
Key Laboratory of Materials Physics, Institute of Solid State Physics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China.
Scinece Island Branch, Graduate School, University of Science and Technology of China, Hefei 230026, China.
Materials (Basel). 2022 Mar 25;15(7):2416. doi: 10.3390/ma15072416.
In this study, oxide dispersion-strengthened Cu alloy with a YO content of 1 wt.% was fabricated through citric acid sol-gel synthesis and spark plasma sintering (SPS). The citric acid sol-gel method provides molecular mixing for the preparation of precursor powders, which produces nanoscale and uniformly distributed YO particles in an ultrafine-grained Cu matrix. The effects of nanoscale YO particles on the microstructure, mechanical properties and thermal conductivity of the Cu-1wt.%YO alloy were investigated. The average grain size of the Cu-1wt.%YO alloy is 0.42 μm, while the average particle size of YO is 16.4 nm. The unique microstructure provides excellent mechanical properties with a tensile strength of 572 MPa and a total elongation of 6.4%. After annealing at 800 °C for 1 h, the strength of the alloy does not decrease obviously, showing excellent thermal stability. The thermal conductivity of Cu-1wt.%YO alloy is about 308 WmK at room temperature and it decreases with increasing temperature. The refined grain size, high strength and excellent thermal stability of Cu-1wt.%YO alloys can be ascribed to the pinning effects of nanoscale YO particles dispersed in the Cu matrix. The Cu-YO alloys with high strength and high thermal conductivity have potential applications in high thermal load components of fusion reactors.
在本研究中,通过柠檬酸溶胶-凝胶合成法和放电等离子烧结(SPS)制备了YO含量为1 wt.%的氧化物弥散强化铜合金。柠檬酸溶胶-凝胶法为前驱体粉末的制备提供了分子混合,从而在超细晶粒铜基体中生成纳米级且均匀分布的YO颗粒。研究了纳米级YO颗粒对Cu-1wt.%YO合金的微观结构、力学性能和热导率的影响。Cu-1wt.%YO合金的平均晶粒尺寸为0.42μm,而YO的平均粒径为16.4nm。这种独特的微观结构具有优异的力学性能,抗拉强度为572MPa,总伸长率为6.4%。在800℃退火1h后,合金强度没有明显下降,表现出优异的热稳定性。Cu-1wt.%YO合金在室温下的热导率约为308W/(m·K),并且随温度升高而降低。Cu-1wt.%YO合金细化的晶粒尺寸、高强度和优异的热稳定性可归因于分散在铜基体中的纳米级YO颗粒的钉扎效应。具有高强度和高导热率的Cu-YO合金在聚变反应堆的高热负荷部件中具有潜在应用。