Liu Chengxin, Cui Jin, Wang Yufang, Zhang Mingjie
Department of Chemistry, School of Sciences, Tianjin University Tianjin 30035 P. R. China.
National Foodstuff Inspection Center, Tianjin Product Quality Inspection Technology Research Institute Tianjin 300384 P. R. China.
RSC Adv. 2021 Mar 22;11(19):11739-11744. doi: 10.1039/d1ra00248a. eCollection 2021 Mar 16.
A novel metal-organic framework (MOF) with two-dimensional (2D) crystal structure was developed using Cu(NO)·3HO and 2,2',5,5'-tetramethoxy-[1,1'-biphenyl]-4,4'-dicarboxylic acid. Further, its structure was characterized using infrared spectroscopy, thermogravimetry, X-ray diffraction, and X-ray crystallography. The activated Cu-MOF was used to catalyze the dehydrogenative oxidation of alcohol and -arylation of azole compounds. Furthermore, it could be easily recovered and reused.
使用硝酸铜·3水合物和2,2',5,5'-四甲氧基-[1,1'-联苯]-4,4'-二羧酸合成了一种具有二维晶体结构的新型金属有机框架（MOF）。此外，通过红外光谱、热重分析、X射线衍射和X射线晶体学对其结构进行了表征。活化后的铜基MOF用于催化醇的脱氢氧化反应和唑类化合物的芳基化反应。此外，它可以很容易地回收和重复使用。
