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不同MgO含量改性粉煤灰上的甲烷干重整反应

The dry reforming of methane over fly ash modified with different content levels of MgO.

作者信息

Huang Yufan, Li Qi, Zhao Teng, Zhu Xiaofeng, Wang Zijun

机构信息

School of Chemistry and Chemical Engineering, Shihezi University Shihezi Xinjiang 832003 PR China

Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Key Laboratory of Materials-Oriented Chemical Engineering of Xinjiang Uygur Autonomous Region, Engineering Research Center of Materials-Oriented Chemical Engineering of Xinjiang Bingtuan Shihezi Xinjiang 832003 PR China.

出版信息

RSC Adv. 2021 Apr 14;11(23):14154-14160. doi: 10.1039/d1ra01381e. eCollection 2021 Apr 13.

Abstract

Large amounts of industrial waste fly ash (FA) have caused serious pollution to the environment. There are a few reports that this kind of material, with its good thermal stability, can be used as a catalyst support for high-temperature catalytic reactions, and it has a certain application space. Upon the alkali treatment of fly ash, its specific surface area is increased, and it has the potential to be a catalyst support. Using treated fly ash as the carrier, a nickel-based catalyst was prepared a sol-gel method, and the catalytic performance changes of catalysts with different MgO content levels in the dry reforming of methane are discussed. Under the conditions of a space velocity of 1.8 × 10 mL g h and a reaction temperature of 750 °C, in the presence of Ni/NaFA-M2 (M2 = 20 wt% MgO), the CH conversion rate can reach 84%, and it has good reaction stability. This will provide a way to use fly ash and carry out more research.

摘要

大量的工业废渣粉煤灰(FA)已对环境造成严重污染。有一些报道称,这种具有良好热稳定性的材料可作为高温催化反应的催化剂载体,且具有一定的应用空间。对粉煤灰进行碱处理后,其比表面积增大,有潜力成为催化剂载体。以处理后的粉煤灰为载体,采用溶胶-凝胶法制备了镍基催化剂,并讨论了不同MgO含量水平的催化剂在甲烷干重整反应中的催化性能变化。在空速为1.8×10 mL g h和反应温度为750℃的条件下,在Ni/NaFA-M2(M2 = 20 wt% MgO)存在下,CH转化率可达84%,且具有良好的反应稳定性。这将为粉煤灰的利用提供一条途径,并开展更多研究。

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