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用于增强通过选择性激光烧结制备的PA12复合材料热导率的AlO与BN的组合。

The combination of AlO and BN for enhancing the thermal conductivity of PA12 composites prepared by selective laser sintering.

作者信息

Yuan Yue, Wu Wei, Hu Huanbo, Liu Dongmei, Shen Hui, Wang Zhengyi

机构信息

Sino-German Joint Research Center of Advanced Materials, School of Materials Science and Engineering, East China University of Science and Technology Shanghai 200237 PR China

Oechsler Plastic Products (Taicang) Co., Ltd. Suzhou 215000 PR China.

出版信息

RSC Adv. 2021 Jan 7;11(4):1984-1991. doi: 10.1039/d0ra09775f. eCollection 2021 Jan 6.

Abstract

A powder-based 3D printing technology, selective laser sintering (SLS), is a novel strategy of manufacturing complex components with specially tailored properties, including mechanical properties, as well as thermal and electrical conductivity. In this study, the effect of incorporating AlO particles and BN plates on the thermal conductivity of PA12 composites was investigated. PA12 composite powders, which can be well applied to SLS, were prepared a two-step approach to mixing. Morphology characteristics demonstrated that the fillers dispersed uniformly in the PA12 matrix, as expected. With 35 wt% AlO and 15 wt% BN hybrid fillers, the tensile strength had the potential to reach 25.7 MPa, while the thermal conductivity could reach 1.05 W m K, 275% higher than that of pure PA12. In addition, the study investigated the effects of filler content on the thermal stability and mechanical properties whilst analysing the melting and crystallisation behaviours of SLS components. The results demonstrate that these composites have favourable thermal stability and exhibit no severe deterioration in mechanical properties. The PA12 composites prepared in this work therefore illustrated vast potential in thermal management materials.

摘要

一种基于粉末的3D打印技术,即选择性激光烧结(SLS),是制造具有特殊定制性能(包括机械性能以及热导率和电导率)的复杂部件的新策略。在本研究中,研究了掺入AlO颗粒和BN片对PA12复合材料热导率的影响。采用两步混合法制备了可很好应用于SLS的PA12复合粉末。形态特征表明,填料如预期那样均匀分散在PA12基体中。含有35 wt% AlO和15 wt% BN混合填料时,拉伸强度有潜力达到25.7 MPa,而热导率可达1.05 W m K,比纯PA12高275%。此外,该研究在分析SLS部件的熔融和结晶行为的同时,研究了填料含量对热稳定性和机械性能的影响。结果表明,这些复合材料具有良好的热稳定性,且机械性能没有严重下降。因此,本工作制备的PA12复合材料在热管理材料方面显示出巨大潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db94/8693637/14642034c3e7/d0ra09775f-f1.jpg

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