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基于SiO非晶态光子晶体通过添加双功能黑色TiO纳米颗粒开发新型催化颜料。

The Development of New Catalytic Pigments Based on SiO Amorphous Photonic Crystals via Adding of Dual-Functional Black TiO Nanoparticles.

作者信息

Feng Li, Luo Hongjie, Wang Fen, Zhao Ting, Wei Xiaohong, Zhu Jianfeng, Qin Yi

机构信息

Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xian, Shaanxi 710021, China.

School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China.

出版信息

ACS Omega. 2022 Apr 1;7(14):12089-12097. doi: 10.1021/acsomega.2c00346. eCollection 2022 Apr 12.

Abstract

Biomimetic synthesis of amorphous photonic crystals (APCs) is an effective approach to obtaining non-iridescent structural colors. However, the structural colors of artificially prepared APCs are dim or even white due to the influence of incoherent scattering. In this paper, we present a novel method to combine APCs with black TiO to construct a noniridescent structural color pigments with high visibility and photocatalytic activity. Due to the absorption of incoherently scattered light by black TiO , the color saturation of structural colors has been significantly increased. In addition, the utilization rate of photogenic carriers was effectively enhanced by the slow light effect generated from the pseudoband gap of SiO APCs with TiO absorbed full spectrum. The tone and color saturation of catalytic pigments is controlled by the diameter of SiO nanospheres and the ratio of TiO nanoparticles, which provides a controllable application study in color-related fields as artwork, environmental coatings, and textiles.

摘要

非晶态光子晶体(APCs)的仿生合成是获得非虹彩结构色的有效方法。然而,由于非相干散射的影响,人工制备的APCs的结构色暗淡甚至呈白色。在本文中,我们提出了一种将APCs与黑色TiO相结合的新方法,以构建具有高可见度和光催化活性的非虹彩结构色颜料。由于黑色TiO对非相干散射光的吸收,结构色的色彩饱和度显著提高。此外,通过SiO APCs的赝带隙产生的慢光效应,有效提高了光生载流子的利用率,其中TiO吸收了全光谱。催化颜料的色调和色彩饱和度由SiO纳米球的直径和TiO纳米颗粒的比例控制,这为在艺术作品、环境涂料和纺织品等与颜色相关的领域提供了可控的应用研究。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1409/9016863/3a690e65cfb0/ao2c00346_0005.jpg

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