• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

置换反应辅助合成亚纳米级Pt/Bi助力耐甲醇燃料电池

Displacement Reaction-Assisted Synthesis of Sub-Nanometer Pt/Bi Boost Methanol-Tolerant Fuel Cells.

作者信息

Wu Xianling, Wang Dumei, Kang Xueming, Zhang Dongtang, Yan Yong, Guo Guangsheng, Sun Zaicheng, Wang Xiayan

机构信息

Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, Beijing 100124, China.

Minzu University of China, Beijing 100081, China.

出版信息

Nanomaterials (Basel). 2022 Apr 11;12(8):1301. doi: 10.3390/nano12081301.

DOI:10.3390/nano12081301
PMID:35458008
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9025715/
Abstract

The development of new synthetic methods for methanol-tolerant catalysts with improved performance is of fundamental importance for the commercialization of fuel cells. Herein, we reported a facile displacement reaction-assisted synthesis of graphene-supported sub-nanometer Pt/Bi catalysts (Pt/Bi/rGO). Bismuth (0) nanoparticles produced by NHBH reduction can be further dissolved into the ethylene glycol, implying Bi(0) has a strong interaction with the hydroxyl group. That is the key interaction between Bi(0) and the functional group on the rGO to form the ultra-small Bi/rGO catalyst. Furthermore, Pt clusters are obtained by the displacement between Bi(0) and HPtCl and are directly anchored to the rGO surface. The as-synthesized Pt/Bi/rGO catalyst exhibits high oxygen reduction mass activity and high tolerance to methanol poisoning. In the presence of 0.5 mol/L CHOH, the initial potential and activity of ORR were almost unchanged, which demonstrated great potential in the application of direct methanol fuel cells.

摘要

开发具有更高性能的耐甲醇催化剂的新合成方法对于燃料电池商业化至关重要。在此，我们报道了一种简便的置换反应辅助合成石墨烯负载的亚纳米Pt/Bi催化剂（Pt/Bi/rGO）的方法。由NHBH还原产生的铋（0）纳米颗粒可进一步溶解于乙二醇中，这意味着Bi(0)与羟基有很强的相互作用。这是Bi(0)与rGO上的官能团形成超小Bi/rGO催化剂的关键相互作用。此外，通过Bi(0)与HPtCl之间的置换获得Pt簇，并直接锚定在rGO表面。所合成的Pt/Bi/rGO催化剂表现出高的氧还原质量活性和对甲醇中毒的高耐受性。在0.5 mol/L CH₃OH存在下，ORR的初始电位和活性几乎不变，这表明其在直接甲醇燃料电池应用中具有巨大潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a137/9025715/2544cb7ec30c/nanomaterials-12-01301-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a137/9025715/f949da53f992/nanomaterials-12-01301-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a137/9025715/41530daae1f2/nanomaterials-12-01301-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a137/9025715/532d45467fa6/nanomaterials-12-01301-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a137/9025715/54f6393fab28/nanomaterials-12-01301-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a137/9025715/2544cb7ec30c/nanomaterials-12-01301-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a137/9025715/f949da53f992/nanomaterials-12-01301-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a137/9025715/41530daae1f2/nanomaterials-12-01301-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a137/9025715/532d45467fa6/nanomaterials-12-01301-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a137/9025715/54f6393fab28/nanomaterials-12-01301-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a137/9025715/2544cb7ec30c/nanomaterials-12-01301-g005.jpg

相似文献

1
Displacement Reaction-Assisted Synthesis of Sub-Nanometer Pt/Bi Boost Methanol-Tolerant Fuel Cells.置换反应辅助合成亚纳米级Pt/Bi助力耐甲醇燃料电池
Nanomaterials (Basel). 2022 Apr 11;12(8):1301. doi: 10.3390/nano12081301.
2
Synthesis and Characterization of Nitrogen Doped Reduced Graphene Oxide (N-rGO) Supported PtCu Anode Catalysts for Direct Methanol Fuel Cell.用于直接甲醇燃料电池的氮掺杂还原氧化石墨烯（N-rGO）负载PtCu阳极催化剂的合成与表征
J Nanosci Nanotechnol. 2019 Jul 1;19(7):3832-3843. doi: 10.1166/jnn.2019.16301.
3
One-Step Microwave-Assisted Synthesis of PtNiCo/rGO Electrocatalysts with High Electrochemical Performance for Direct Methanol Fuel Cells.一步微波辅助合成用于直接甲醇燃料电池的具有高电化学性能的PtNiCo/rGO电催化剂
Nanomaterials (Basel). 2021 Aug 27;11(9):2206. doi: 10.3390/nano11092206.
4
One-pot solvothermal synthesis of reduced graphene oxide-supported uniform PtCo nanocrystals for efficient and robust electrocatalysis.一锅溶剂热法合成还原氧化石墨烯负载的均匀 PtCo 纳米晶用于高效稳定的电催化。
J Colloid Interface Sci. 2019 May 1;543:17-24. doi: 10.1016/j.jcis.2019.01.110. Epub 2019 Jan 28.
5
Synthesis and Characterization of PtCo Alloy Nanoparticles Supported on a Reduced Graphene Oxide/g-C₃N₄ Composite for Efficient Methanol Electro-Oxidation.负载于还原氧化石墨烯/g-C₃N₄复合材料上的PtCo合金纳米颗粒的合成与表征用于高效甲醇电氧化
J Nanosci Nanotechnol. 2021 Mar 1;21(3):1721-1727. doi: 10.1166/jnn.2021.18992.
6
High-Performance Direct Methanol Fuel Cells with Precious-Metal-Free Cathode.具有无贵金属阴极的高性能直接甲醇燃料电池。
Adv Sci (Weinh). 2016 Jun 14;3(11):1600140. doi: 10.1002/advs.201600140. eCollection 2016 Nov.
7
Dicyanamide Anion-Based Ionic Liquid-Functionalized Graphene-Supported Pt Catalysts for Boosting Methanol Electrooxidation.基于双氰胺阴离子的离子液体功能化石墨烯负载铂催化剂用于促进甲醇电氧化
Inorg Chem. 2021 Sep 6;60(17):13736-13747. doi: 10.1021/acs.inorgchem.1c02111. Epub 2021 Aug 26.
8
Enhanced electrocatalytic activity of Pt nanoparticles supported on functionalized graphene for methanol oxidation and oxygen reduction.功能化石墨烯负载的铂纳米颗粒对甲醇氧化和氧还原的电催化活性增强。
J Colloid Interface Sci. 2015 Nov 1;457:102-7. doi: 10.1016/j.jcis.2015.06.031. Epub 2015 Jun 23.
9
Gallic acid-assisted synthesis of Pd uniformly anchored on porous N-rGO as efficient electrocatalyst for microbial fuel cells.没食子酸辅助合成均匀锚定在多孔氮掺杂还原氧化石墨烯上的钯作为微生物燃料电池的高效电催化剂。
Dalton Trans. 2018 Jan 30;47(5):1442-1450. doi: 10.1039/c7dt04063f.
10
Self-assembled platinum nanoparticles on sulfonic acid-grafted graphene as effective electrocatalysts for methanol oxidation in direct methanol fuel cells.磺酸接枝石墨烯上自组装的铂纳米颗粒作为直接甲醇燃料电池中甲醇氧化的有效电催化剂。
Sci Rep. 2016 Feb 15;6:21530. doi: 10.1038/srep21530.

引用本文的文献

1
Quantum Revivals in Curved Graphene Nanoflakes.弯曲石墨烯纳米薄片中的量子复苏
Nanomaterials (Basel). 2022 Jun 7;12(12):1953. doi: 10.3390/nano12121953.

本文引用的文献

1
One-Step Microwave-Assisted Synthesis of PtNiCo/rGO Electrocatalysts with High Electrochemical Performance for Direct Methanol Fuel Cells.一步微波辅助合成用于直接甲醇燃料电池的具有高电化学性能的PtNiCo/rGO电催化剂
Nanomaterials (Basel). 2021 Aug 27;11(9):2206. doi: 10.3390/nano11092206.
2
Single-atom catalyst for high-performance methanol oxidation.用于高性能甲醇氧化的单原子催化剂。
Nat Commun. 2021 Sep 2;12(1):5235. doi: 10.1038/s41467-021-25562-y.
3
Ultrathin PdAuBiTe Nanosheets as High-Performance Oxygen Reduction Catalysts for a Direct Methanol Fuel Cell Device.
超薄PdAuBiTe纳米片作为直接甲醇燃料电池装置的高性能氧还原催化剂
Adv Mater. 2021 Oct;33(42):e2103383. doi: 10.1002/adma.202103383. Epub 2021 Aug 31.
4
Intermetallic FePt@PtBi Core-Shell Nanoparticles for Oxygen Reduction Electrocatalysis.用于氧还原电催化的金属间化合物FePt@PtBi核壳纳米颗粒
Angew Chem Int Ed Engl. 2021 Sep 27;60(40):21899-21904. doi: 10.1002/anie.202107437. Epub 2021 Aug 31.
5
Single-atom catalysis in advanced oxidation processes for environmental remediation.单原子催化在环境修复高级氧化过程中的应用。
Chem Soc Rev. 2021 Apr 26;50(8):5281-5322. doi: 10.1039/d0cs01032d.
6
Theoretical Understandings of Graphene-based Metal Single-Atom Catalysts: Stability and Catalytic Performance.基于石墨烯的金属单原子催化剂的理论理解：稳定性与催化性能
Chem Rev. 2020 Nov 11;120(21):12315-12341. doi: 10.1021/acs.chemrev.0c00818. Epub 2020 Oct 28.
7
Carbon-Supported Divacancy-Anchored Platinum Single-Atom Electrocatalysts with Superhigh Pt Utilization for the Oxygen Reduction Reaction.用于氧还原反应的具有超高铂利用率的碳负载双空位锚定铂单原子电催化剂
Angew Chem Int Ed Engl. 2019 Jan 21;58(4):1163-1167. doi: 10.1002/anie.201812423. Epub 2018 Dec 20.
8
Self-Healing Proton-Exchange Membranes Composed of Nafion-Poly(vinyl alcohol) Complexes for Durable Direct Methanol Fuel Cells.基于 Nafion-聚乙烯醇复合物的自修复质子交换膜用于长寿命直接甲醇燃料电池。
Adv Mater. 2018 Jun;30(25):e1707146. doi: 10.1002/adma.201707146. Epub 2018 Apr 30.
9
One-Step, Facile and Ultrafast Synthesis of Phase- and Size-Controlled Pt-Bi Intermetallic Nanocatalysts through Continuous-Flow Microfluidics.通过连续流微流控技术一步法、简便快速合成具有可控相和尺寸的 Pt-Bi 金属间化合物纳米催化剂。
J Am Chem Soc. 2015 May 20;137(19):6263-9. doi: 10.1021/jacs.5b01088. Epub 2015 May 7.
10
Platinum-modified covalent triazine frameworks hybridized with carbon nanoparticles as methanol-tolerant oxygen reduction electrocatalysts.铂修饰的共价三嗪框架与碳纳米颗粒杂化作为耐甲醇氧还原电催化剂。
Nat Commun. 2014 Sep 22;5:5040. doi: 10.1038/ncomms6040.