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基于生物炭过硫酸盐的高级氧化工艺在修复有机化合物污染地下水和土壤中的应用及影响因素。

Applications and influencing factors of the biochar-persulfate based advanced oxidation processes for the remediation of groundwater and soil contaminated with organic compounds.

机构信息

College of Resources and Environment, Hunan Agricultural University, Changsha 410128, China.

School of Biology and Chemistry, Key Laboratory of Chemical Synthesis and Environmental Pollution Control-Remediation Technology of Guizhou Province, Minzu Normal University of Xingyi, Xingyi 562400, China.

出版信息

Sci Total Environ. 2022 Aug 25;836:155421. doi: 10.1016/j.scitotenv.2022.155421. Epub 2022 Apr 25.

Abstract

Biochar (BC) is a low-cost material rich in carbon, which is being used increasingly as a catalyst in persulfate-based advanced oxidation processes (PS-AOPs) for the remediation of groundwater and soil contaminated with organic compounds. In this work, a general summary of preparation methods and applications of various BC (i.e., pristine BC, magnetic BC, and chemically modified BC) in PS-AOPs is presented. Different influence factors (e.g., pH, anions, natural organic matter) for the degradation of organic compounds are discussed. Meanwhile, the influence of external energy (e.g., solar irradiation, UV-Vis, ultrasonic) is also mentioned. Furthermore, the advantage of different BC in PS-AOPs are compared. Finally, potential problems, challenges, and prospects in the application of biochar-persulfate based advanced oxidation processes (BCPS-AOPs) are discussed in the conclusion and perspective.

摘要

生物炭(BC)是一种富含碳的低成本材料,作为过硫酸盐基高级氧化工艺(PS-AOPs)中的催化剂,越来越多地用于修复受有机化合物污染的地下水和土壤。在这项工作中,对各种生物炭(即原始生物炭、磁性生物炭和化学改性生物炭)在 PS-AOPs 中的制备方法和应用进行了综合概述。讨论了影响有机化合物降解的不同影响因素(例如 pH 值、阴离子、天然有机物)。同时,还提到了外部能量(例如太阳辐射、UV-Vis、超声)的影响。此外,还比较了不同生物炭在 PS-AOPs 中的优势。最后,在结论和展望部分讨论了生物炭-过硫酸盐基高级氧化工艺(BCPS-AOPs)应用中的潜在问题、挑战和前景。

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