Key Laboratory of Karst Georesources and Environment (Guizhou University), Ministry of Education, Guiyang, Guizhou 550025, China.
Key Laboratory of Karst Georesources and Environment (Guizhou University), Ministry of Education, Guiyang, Guizhou 550025, China; College of Resources and Environmental Engineering, Guizhou University, Guiyang, Guizhou 550025, China.
J Hazard Mater. 2023 Jan 15;442:130075. doi: 10.1016/j.jhazmat.2022.130075. Epub 2022 Sep 29.
Biochar has shown large potential in environmental remediation because of its low cost, large specific surface area, porosity, and high conductivity. Biochar-assisted advanced oxidation processes (BC-AOPs) have recently attracted increasing attention to the remediation of organic pollutants from water. However, the effects of biochar properties on catalytic performance need to be further explored. There are still controversial and knowledge gaps in the reaction mechanisms of BC-AOPs, and regeneration methods of biochar catalysts are lacking. Therefore, it is necessary to systematically review the latest research progress of BC-AOPs in the treatment of organic pollutants in water. In this review, first of all, the effects of biochar properties on catalytic activity are summarized. The biochar properties can be optimized by changing the feedstocks, preparation conditions, and modification methods. Secondly, the catalytic active sites and degradation mechanisms are explored in different BC-AOPs. Different influencing factors on the degradation process are analyzed. Then, the applications of BC-AOPs in environmental remediation and regeneration methods of different biochar catalysts are summarized. Finally, the development prospects and challenges of biochar catalysts in environmental remediation are put forward, and some suggestions for future development are proposed.
生物炭由于其低成本、大比表面积、孔隙率和高导电性,在环境修复中显示出巨大的潜力。生物炭辅助的高级氧化工艺(BC-AOPs)最近越来越受到关注,用于水相有机污染物的修复。然而,生物炭性质对催化性能的影响需要进一步探索。BC-AOPs 的反应机制仍存在争议和知识空白,生物炭催化剂的再生方法也缺乏。因此,有必要系统地综述 BC-AOPs 在处理水中有机污染物方面的最新研究进展。在本文中,首先总结了生物炭性质对催化活性的影响。通过改变原料、制备条件和改性方法,可以优化生物炭的性质。其次,探讨了不同 BC-AOPs 中的催化活性位点和降解机制。分析了不同影响因素对降解过程的影响。然后,总结了 BC-AOPs 在环境修复中的应用以及不同生物炭催化剂的再生方法。最后,提出了生物炭催化剂在环境修复中的发展前景和挑战,并提出了一些未来发展的建议。