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一种用于海上油田的有机/无机复合凝胶堵漏体系的合成与性能评价

Synthesis and Performance Evaluation of an Organic/Inorganic Composite Gel Plugging System for Offshore Oilfields.

作者信息

Xie Kun, Su Cheng, Liu Changlong, Cao Weijia, He Xin, Ding Hongna, Mei Jie, Yan Kun, Cheng Qian, Lu Xiangguo

机构信息

Laboratory of Enhanced Oil Recovery of Education Ministry, Northeast Petroleum University College of Petroleum Engineering, Daqing 163318, P. R. China.

Bohai Olilfeld Research Institute, Tianjin Branch of CNOOC (China) Co., Ltd., Tianjin Binhai New Area Bohai Petroleum 688 Petroleum Building, Tianjin 300459, P. R. China.

出版信息

ACS Omega. 2022 Apr 5;7(15):12870-12878. doi: 10.1021/acsomega.2c00133. eCollection 2022 Apr 19.

Abstract

In this article, we developed a new composite gel for plugging dominant fluid flow channels in offshore oilfields. The composite gel was synthesized by organic and inorganic gel networks interpenetrating into a compact three-dimensional spatial network structure, resulting in a good plugging effect. The performance of the composite gel was evaluated from the aspects of gelling characteristics and gel microstructure, while the plugging effect was evaluated through core experiments. The results showed that the influencing order of each component on gelling was acrylamide > cross-linking agent > urea > initiator > polyaluminum chloride. The initial viscosity of the composite gel was about 5-6 mPa·s, and it had good plugging abilities in different permeability cores. In comparison with inorganic gels (plugging ratio of 77.2%) or organic gels (84.8%), the composite gel system has a plugging ratio of up to 99.5% using a core with water permeability of 4300 mD. Besides, the reservoir applicability of the composite gel was studied, and the results suggested that the composite gel system had good resistance to dilution, mechanical shear, oil corrosion, and aging and could be quickly removed after plugging.

摘要

在本文中,我们开发了一种新型复合凝胶,用于封堵海上油田的主要流体流动通道。该复合凝胶是通过有机和无机凝胶网络相互贯穿形成紧密的三维空间网络结构而合成的,具有良好的封堵效果。从凝胶特性和凝胶微观结构方面对复合凝胶的性能进行了评价,同时通过岩心实验对封堵效果进行了评价。结果表明,各组分对凝胶化的影响顺序为:丙烯酰胺>交联剂>尿素>引发剂>聚合氯化铝。复合凝胶的初始粘度约为5-6 mPa·s,在不同渗透率岩心中具有良好的封堵能力。与无机凝胶(封堵率77.2%)或有机凝胶(84.8%)相比,使用渗透率为4300 mD的岩心时,复合凝胶体系的封堵率高达99.5%。此外,研究了复合凝胶的储层适用性,结果表明该复合凝胶体系具有良好的抗稀释、抗机械剪切、抗油腐蚀和抗老化性能,封堵后可快速清除。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e0af/9026030/a3f75497d4b1/ao2c00133_0002.jpg

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