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一种低初始粘度凝胶堵漏剂的制备与实验研究

Preparation and Experimental Study of a Low-Initial-Viscosity Gel Plugging Agent.

作者信息

Huang Bin, Zhang Weisen, Zhou Quan, Fu Cheng, He Shibo

机构信息

Key Laboratory of Enhanced Oil Recovery (Northeast Petroleum University), Ministry of Education; College of Petroleum Engineering, Northeast Petroleum University, Daqing 163318, China.

Post-Doctoral Scientific Research Station, Daqing Oilfield Company, Daqing 163413, China.

出版信息

ACS Omega. 2020 Jun 22;5(25):15715-15727. doi: 10.1021/acsomega.0c02242. eCollection 2020 Jun 30.

Abstract

The development of dominant seepage channels after polymer flooding makes it more difficult to effectively exploit reservoirs, and gel plugging technology is an effective method to solve this problem. However, conventional gels experience problems such as high initial viscosity and they easily contaminate the medium- and low-permeability layers. Therefore, a low-initial-viscosity gel plugging agent is proposed in this paper. By optimizing the concentration of polymer, cross-linking agent, and other functional auxiliaries, the best gel formulation was obtained. To test the plugging ability of the gel system on the core and its oil displacement effect, a plugging performance test experiment and three-tube core parallel oil displacement experiment were performed. The research results showed that the best formulation of gel plugging agent is as follows: 500-1000 mg/L polymer LH2500, 1000-2500 mg/L cross-linking agent CYJL, 200-500 mg/L citric acid, 100-150 mg/L sodium sulfite, and 100-200 mg/L sodium polyphosphate; its initial viscosity is less than 10 mPa·s, the gelation time is controllable within 10 to 40 days, and the gelation viscosity is above 2000 mPa·s. Core flooding experiments showed that the gel system has good core plugging performance, and the plugging rate of water from 0.48 to 3.9 μm is more than 99%; for the secondary polymer flooding reservoir, the recovery factor can be increased by 13.6% after plugging with 0.1 PV gel. At present, the gel has been successfully used in field tests and provides good oil increase and water control effects.

摘要

聚合物驱后优势渗流通道的发育使得油藏有效开发难度增大,凝胶封堵技术是解决这一问题的有效方法。然而,常规凝胶存在初始黏度高、易污染中低渗透层等问题。因此,本文提出了一种低初始黏度凝胶封堵剂。通过优化聚合物、交联剂及其他功能助剂的浓度,得到了最佳凝胶配方。为测试该凝胶体系对岩心的封堵能力及其驱油效果,进行了封堵性能测试实验和三管岩心并联驱油实验。研究结果表明,凝胶封堵剂的最佳配方为:聚合物LH2500浓度500 - 1000 mg/L、交联剂CYJL浓度1000 - 2500 mg/L、柠檬酸浓度200 - 500 mg/L、亚硫酸钠浓度100 - 150 mg/L、三聚磷酸钠浓度100 - 200 mg/L;其初始黏度小于10 mPa·s,成胶时间可控制在10至40天内,成胶黏度大于2000 mPa·s。岩心驱替实验表明,该凝胶体系具有良好的岩心封堵性能,对0.48至3.9μm的水封堵率大于99%;对于二次聚合物驱油藏,注入0.1 PV凝胶封堵后采收率可提高13.6%。目前,该凝胶已成功应用于现场试验,取得了良好的增油控水效果。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9221/7331225/3e962df7fa6e/ao0c02242_0001.jpg

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