Han Guang, Dong Ziwen, Zhao Liangke, Zhang Qianqian
College of Safety Science and Engineering, Liaoning Technical University, Fuxin, Liaoning 123000, China.
School of Safety Engineering, Ningbo University of Technology, Ningbo, Zhejiang 315211, China.
ACS Omega. 2022 Apr 4;7(15):13102-13111. doi: 10.1021/acsomega.2c00521. eCollection 2022 Apr 19.
The spontaneous combustion of coal is affected by many factors, among which the influence of water is significant and complicated. To explore the influence of water on the spontaneous combustion characteristics of goaf residual coal, coal samples with similar particle size distributions to those of goaf residual coal were prepared. After the coal samples were immersed in water for 7-21 days and the external flowing water was drained, spontaneous combustion experiments were carried out using a temperature-programmed method. The results showed that soaking in water could promote and inhibit the spontaneous oxidative combustion of large coal particles in different temperature ranges. When the coal temperature was below 50 °C, water immersion had a significant inhibition effect on coal oxidation and spontaneous combustion. When the temperature of coal was 50-110 °C, soaking in water for 7 days could promote the oxidation and spontaneous combustion of coal. However, soaking for 14 and 21 days had a significant inhibition effect in this temperature range. When the coal temperature was higher than 110 °C, water immersion had a significant inhibition effect on the coal. Moreover, a prolonged immersion time significantly enhanced the inhibition effect. When the immersion time was less than 21 days, the spontaneous combustion of large coal particles by short-term soaking was mainly inhibited.
煤炭自燃受多种因素影响,其中水分的影响显著且复杂。为探究水分对采空区遗煤自燃特性的影响,制备了粒度分布与采空区遗煤相似的煤样。将煤样浸泡在水中7 - 21天,排净外部流水后,采用程序升温法进行自燃实验。结果表明,在不同温度范围内,浸水对大颗粒煤的自燃氧化有促进和抑制作用。当煤温低于50℃时,浸水对煤的氧化和自燃有显著抑制作用。当煤温为50 - 110℃时,浸水7天可促进煤的氧化和自燃。然而,浸水14天和21天在此温度范围内有显著抑制作用。当煤温高于110℃时,浸水对煤有显著抑制作用。而且,延长浸泡时间会显著增强抑制效果。当浸泡时间小于21天时,短期浸水对大颗粒煤自燃的抑制作用主要体现在这方面。