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具有增强近红外反射率的纳米结构FeO/TiO复合颗粒,用于激光雷达可检测的凉爽颜料。

Nanostructured FeO/TiO composite particles with enhanced NIR reflectance for application to LiDAR detectable cool pigments.

作者信息

Lee Hyeon Ju, Jung Kyeong Youl, Kim Young-Seok

机构信息

Department of Chemical Engineering, Kongju National University 1224-24 Cheonan-Daero, Seobuk-gu Cheonan Chungnam 31080 Republic of Korea

Display Research Center, Korea Electronics Technology Institute 25, Saenari-ro, Bundang-gu Seoungnam-si Kyounggi-do 13509 Korea.

出版信息

RSC Adv. 2021 May 7;11(28):16834-16840. doi: 10.1039/d1ra02614c. eCollection 2021 May 6.

DOI:10.1039/d1ra02614c
PMID:35479727
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9031897/
Abstract

Nanostructured FeO/TiO composite pigments with improved NIR reflectance were prepared by a homogeneous precipitation method using urea and NHOH. The optical and morphological properties of the resulting pigment were investigated by varying the weight ratio of FeO to TiO and the calcination temperature. The resulting composite pigment has a nanostructure in which FeO nanoparticles of 20-30 nm size are well coated on the surface of TiO (∼100 nm) and the reflectance is greatly improved in the wavelength range of 620-1350 nm. The ratio of FeO to TiO and the calcination temperature were optimized to provide both high NIR reflectance and red color, which were 0.1 and 700 °C. As a result, compared with pure FeO ( = 2.06 eV, * = 22.6), the optimized FeO/TiO composite pigment ( = 2.09 eV, * = 24.8) showed similar color properties and improved NIR reflectance by about 23.8%. In addition, the FeO/TiO composite pigment showed about 62.7% larger reflectance at 905 nm than FeO. According to a temperature rise test under IR illumination, the FeO/TiO composite pigment was confirmed to have improved heat shielding properties. Therefore, the nanostructured FeO/TiO powder could be potentially applied as a LiDAR detectable cool red pigment for autonomous vehicles.

摘要

采用尿素和NHOH通过均匀沉淀法制备了具有改善近红外反射率的纳米结构FeO/TiO复合颜料。通过改变FeO与TiO的重量比和煅烧温度,研究了所得颜料的光学和形态学性质。所得复合颜料具有纳米结构,其中尺寸为20 - 30 nm的FeO纳米颗粒良好地包覆在TiO(约100 nm)表面,并且在620 - 1350 nm波长范围内反射率得到极大提高。优化了FeO与TiO的比例以及煅烧温度,以同时提供高近红外反射率和红色,分别为0.1和700°C。结果,与纯FeO(= 2.06 eV,* = 22.6)相比,优化后的FeO/TiO复合颜料(= 2.09 eV,* = 24.8)表现出相似的颜色特性,近红外反射率提高了约23.8%。此外,FeO/TiO复合颜料在905 nm处的反射率比FeO大62.7%左右。根据红外光照下的升温测试,证实FeO/TiO复合颜料具有改善的隔热性能。因此,纳米结构的FeO/TiO粉末有可能作为用于自动驾驶车辆的激光雷达可检测的冷红色颜料应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d802/9031897/f773f284b809/d1ra02614c-f11.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d802/9031897/e4335511818e/d1ra02614c-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d802/9031897/ced1c7ea9f03/d1ra02614c-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d802/9031897/f773f284b809/d1ra02614c-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d802/9031897/30e6bd384c8c/d1ra02614c-f1.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d802/9031897/15b5830af7ff/d1ra02614c-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d802/9031897/7281e77126ff/d1ra02614c-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d802/9031897/8ff9ead0d385/d1ra02614c-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d802/9031897/fb19652dc925/d1ra02614c-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d802/9031897/e4335511818e/d1ra02614c-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d802/9031897/ced1c7ea9f03/d1ra02614c-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d802/9031897/f773f284b809/d1ra02614c-f11.jpg

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