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3-甲基-1,2,3-三唑鎓-1-二硝基亚甲基叶立德与含能材料设计中两性离子二硝基甲基基团的策略

3-Methyl-1,2,3-triazolium-1-dinitromethylylide and the strategy of zwitterionic dinitromethyl groups in energetic materials design.

作者信息

Wozniak Dominique R, Zeller Matthias, Byrd Edward F C, Piercey Davin G

机构信息

Department of Materials Engineering, Purdue Energetics Research Center, Purdue University 205 Gates Road West Lafayette IN 47904 USA.

Department of Chemistry, Purdue University West Lafayette Indiana 47907 USA.

出版信息

RSC Adv. 2021 May 14;11(29):17710-17714. doi: 10.1039/d1ra00953b. eCollection 2021 May 13.

DOI:10.1039/d1ra00953b
PMID:35480183
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9033220/
Abstract

3-Methyl-1,2,3-triazolium-1-dinitromethylylide, an exemplary zwitterionic energetic molecule, is the first fully-studied energetic material making use of the zwitterionic dinitromethyl functional group. This compound has impact and friction sensitivities of 8 J and 144-160 N respectively with a detonation velocity of 8162 m s.

摘要

3-甲基-1,2,3-三唑鎓-1-二硝基亚甲基叶立德，一种典型的两性离子含能分子，是首个对利用两性离子二硝基甲基官能团的含能材料进行全面研究的物质。该化合物的撞击感度和摩擦感度分别为8 J和144 - 160 N，爆速为8162 m/s。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e82/9033220/57c9d42c110f/d1ra00953b-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e82/9033220/b8d5b15da19d/d1ra00953b-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e82/9033220/f8f2c1c270ce/d1ra00953b-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e82/9033220/bf87a2cad997/d1ra00953b-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e82/9033220/57c9d42c110f/d1ra00953b-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e82/9033220/b8d5b15da19d/d1ra00953b-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e82/9033220/f8f2c1c270ce/d1ra00953b-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e82/9033220/bf87a2cad997/d1ra00953b-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e82/9033220/57c9d42c110f/d1ra00953b-f2.jpg

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