1-咪唑-1-甲醇的晶体结构
Crystal structure of 1-imidazole-1-methanol.
作者信息
Wysocki Megan M, Puzovic Gorana, Dowell Keith L, Reinheimer Eric W, Gerlach Deidra L
机构信息
Department of Chemistry and Biochemistry, University of Wisconsin-Eau Claire, 101 Roosevelt Ave, Eau Claire, WI, 54702, USA.
Rigaku Americas Corporation, 9009 New Trails Drive, The Woodlands, TX, 77381, USA.
出版信息
Acta Crystallogr E Crystallogr Commun. 2022 Mar 10;78(Pt 4):377-380. doi: 10.1107/S2056989022002614. eCollection 2022 Apr 1.
The synthesis and the crystal structure of 1-imidazole-1-methanol, CHNO, are described. This compound comprises an imidazole ring with a methanol group attached at the 1-position affording an imine nitro-gen atom able to receive a hydrogen bond and an alcohol group able to donate to a hydrogen bond. This imidazole methanol crystallizes with monoclinic (2/) symmetry with three symmetry-unique mol-ecules. These three mol-ecules are connected O-H⋯N hydrogen bonding in a head-to-tail configuration to form independent three-membered macrocycles.
描述了1-咪唑-1-甲醇（CHNO）的合成及其晶体结构。该化合物包含一个咪唑环，在1位连接有一个甲醇基团，提供了一个能够接受氢键的亚胺氮原子和一个能够提供氢键的醇基团。这种咪唑甲醇以单斜晶系（2/）对称结晶，有三个对称独立的分子。这三个分子通过O-H⋯N氢键以头对尾的构型相连，形成独立的三元大环。
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