使用水溶性电子存储催化剂使苄基卤化物或烯丙基卤化物与氢进行还原C(sp)-C(sp) 同偶联反应。
Reductive C(sp)-C(sp) homo-coupling of benzyl or allyl halides with H using a water-soluble electron storage catalyst.
作者信息
Yatabe Takeshi, Futakuchi Sayaka, Miyazawa Keishi, Shimauchi Daiki, Takahashi Yukina, Yoon Ki-Seok, Nakai Hidetaka, Ogo Seiji
机构信息
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University 744 Moto-oka, Nishi-ku Fukuoka 819-0395 Japan
International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University 744 Moto-oka, Nishi-ku Fukuoka 819-0395 Japan.
出版信息
RSC Adv. 2021 Dec 9;11(62):39450-39454. doi: 10.1039/d1ra08596d. eCollection 2021 Dec 6.
This paper reports the first example of a reductive C(sp)-C(sp) homo-coupling of benzyl/allyl halides in aqueous solution by using H as an electron source {turnover numbers (TONs) = 0.5-2.3 for 12 h}. This homo-coupling reaction, promoted by visible light, is catalysed by a water-soluble electron storage catalyst (ESC). The reaction mechanism, and four requirements to make it possible, are also described.
本文报道了在水溶液中以H作为电子源实现苄基/烯丙基卤化物还原C(sp)-C(sp)均偶联的首个实例（12小时的转化数（TONs）=0.5 - 2.3）。该均偶联反应由可见光促进，由水溶性电子存储催化剂（ESC）催化。文中还描述了反应机理以及使其成为可能的四个条件。
Zotero 插件