Januszewski Rafał, Orwat Bartosz, Merna Jan, Kownacki Ireneusz
Faculty of Chemistry, Adam Mickiewicz University in Poznan Uniwersytetu Poznanskiego 8 61-614 Poznan Poland
Center for Advanced Technology, Adam Mickiewicz University in Poznan Uniwersytetu Poznanskiego 10 61-614 Poznan Poland.
RSC Adv. 2021 Dec 7;11(62):38956-38960. doi: 10.1039/d1ra07468g. eCollection 2021 Dec 6.
An efficient methodology for the synthesis of two groups of silicon-containing alkenes is reported. It includes a highly regioselective functionalization of 1,5-hexadiene through hydrosilylation and dehydrogenative silylation with organofunctional silanes and siloxanes. The established conditions enable selective monofunctionalization of 1,5-hexadiene regardless of the organosilicon modifier used as well as the type of functional group bonded to the silicon-based compound. All products were isolated and fully characterized by NMR spectroscopy and MS techniques.
报道了一种合成两组含硅烯烃的有效方法。该方法包括通过与有机官能硅烷和硅氧烷进行硅氢化反应和脱氢硅烷化反应，对1,5-己二烯进行高度区域选择性官能化。所建立的条件能够实现1,5-己二烯的选择性单官能化，而不管所使用的有机硅改性剂以及与硅基化合物键合的官能团类型如何。所有产物均通过核磁共振光谱和质谱技术进行分离和全面表征。
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