Four new series of chalcones containing imidazole bromonium and benzimidazole bromonium salts with spacer alkyl chains (C , = 2 and 4) were synthesized and the chemical structure, thermal behavior, photoluminescence and gas sensing were characterized by several technical methods. The studies have indicated similar mesomorphic properties of the synthesized compounds, dependent on the terminal alkyl-chain and lengths of the alkoxy-spacer. Almost compounds with shorter alky chains, 4a-4e, 5a-5c, 6a-6c and 7a-7d, did not show liquid crystal properties, while the results of other compounds confirm the existence of smectic A in cooling and heating cycles. Photoluminescence of compounds 5a-5i and 7a-7i was also studied. The emission in the blue region reveals that the material has blue light emission properties. Sensing behavior of compounds 4i and 5i was investigated for NH and NO gases. The sensors exhibited high sensitivity toward NH, while sensitivity toward the oxidizing gas NO is lower.