Gao Qing, Zang Yang, Xie Ju, Wu Yongchuan, Xue Huaiguo
School of Chemistry and Chemical Engineering, Yangzhou University Yangzhou Jiangsu 225002 P. R. China
RSC Adv. 2021 Nov 17;11(58):36769-36776. doi: 10.1039/d1ra04924k. eCollection 2021 Nov 10.
In this work, an electrochemical sensor was designed for trace monitoring of bisphenol A (BPA) by decorating a hybrid bilayer molecularly imprinted membrane (MIM) on a multi-walled carbon nanotube-modified glassy carbon electrode. When BPA in the MIM was eluted, a composite molecularly imprinted electrochemical sensor was constructed. Under optimal conditions, the developed sensor showed two linear relationships between Δ and BPA concentration in the range of 0.04 μM to 8 μM, as well as good selectivity and stability, and was also applied to detect BPA in water samples with desirable recoveries ranging from 92.0% to 107.0%.
在本工作中,通过在多壁碳纳米管修饰的玻碳电极上修饰混合双层分子印迹膜(MIM),设计了一种用于痕量监测双酚A(BPA)的电化学传感器。当MIM中的BPA被洗脱后,构建了一种复合分子印迹电化学传感器。在最佳条件下,所开发的传感器在0.04 μM至8 μM范围内的Δ与BPA浓度之间呈现出两种线性关系,具有良好的选择性和稳定性,并且还应用于检测水样中的BPA,回收率在92.0%至107.0%之间,结果令人满意。