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水 - 氯化钠液滴在声悬浮中的蒸发与干燥动力学

Evaporation and drying kinetics of water-NaCl droplets acoustic levitation.

作者信息

Maruyama Yutaro, Hasegawa Koji

机构信息

Graduate School of Engineering, Kogakuin University Tokyo 163-8677 Japan.

Department of Mechanical Engineering, Kogakuin University Tokyo 163-8677 Japan

出版信息

RSC Adv. 2020 Jan 8;10(4):1870-1877. doi: 10.1039/c9ra09395h.

Abstract

The acoustic levitation method (ALM) is expected to be applied as a container-less processing technology in the material science, analytical chemistry, biomedical technology, and food science domains because this method can be used to levitate any sample in mid-air and prevent nucleation and contamination due to the container wall. However, this approach can lead to nonlinear behavior, such as acoustic streaming, which promotes the evaporation of a levitated droplet. This study aims to understand the evaporation and precipitation kinetics of an acoustically levitated multicomponent droplet. An experimental investigation of the evaporation process of a salt solution droplet was performed, and the experimental results were compared with those of the -law. The droplet was noted to evaporate in two stages owing to the precipitation of the salt. Because of the vapor pressure depression, the experimental data did not agree with the classical prediction obtained using the -law. However, the experimental results were in partial agreement with those of the -law when the vapor pressure depression was considered by using the concentration estimate at each time, as obtained from the experimental results. In addition, it was observed that the time when the salt completely precipitated could be estimated by using the extended theory. These findings provide physical and practical insights into the droplet evaporation mid-air for potential lab-in-a-drop applications.

摘要

声悬浮法(ALM)有望作为一种无容器处理技术应用于材料科学、分析化学、生物医学技术和食品科学领域,因为该方法可用于使任何样品悬浮于空中,并防止由于容器壁导致的成核和污染。然而,这种方法可能会导致非线性行为,如声流,从而促进悬浮液滴的蒸发。本研究旨在了解声悬浮多组分液滴的蒸发和沉淀动力学。对盐溶液液滴的蒸发过程进行了实验研究,并将实验结果与 - 定律的结果进行了比较。由于盐的沉淀,液滴被观察到分两个阶段蒸发。由于蒸气压降低,实验数据与使用 - 定律获得的经典预测不一致。然而,当使用从实验结果获得的每次浓度估计值来考虑蒸气压降低时,实验结果与 - 定律的结果部分一致。此外,观察到可以使用扩展理论来估计盐完全沉淀的时间。这些发现为潜在的液滴实验室应用中液滴在空中蒸发提供了物理和实际的见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2305/9048286/a78eba328482/c9ra09395h-f1.jpg

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