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用无色染料封装的微胶囊作为用于混凝土损伤指示颜色变化的视觉传感器。

Microcapsule encapsulated with leuco dye as a visual sensor for concrete damage indication color variation.

作者信息

Li Yao, Wang Qing, Zheng Xu, Li Yunfeng, Luan Jinjin

机构信息

Institute of NanoEngineering, College of Civil Engineering and Architecture, Shandong University of Science and Technology Qingdao 266590 China

出版信息

RSC Adv. 2020 Jan 8;10(3):1226-1231. doi: 10.1039/c9ra09492j. eCollection 2020 Jan 7.

Abstract

A microcapsule-type visualization sensor for concrete structural damage indication is proposed in this article. Crystal violet lactone, as damage indicator, was microencapsulated within poly(methyl methacrylate) to synthesize the sensor. The successful encapsulation was confirmed by Fourier transform infrared spectrometry. Microcapsules of different diameters and size distributions were obtained by varied stirring speeds. The fabricated microcapsules were embedded into a polymer coating to accomplish the damage indication. When cracks propagated in the coating, the crystal violet lactone in leuco form was released from the ruptured microcapsules. Due to reacting with silicon dioxide in concrete, the released crystal violet lactone turned blue and highlighted the damaged area. It was verified that the visualization performance of the sensor showed good durability in both dry and wet conditions. The proposed microcapsule-type visualization sensor has advantages of easy fabrication, high indication stability, and no special equipment requirements, which will reduce the complexity of concrete structural health monitoring significantly.

摘要

本文提出了一种用于混凝土结构损伤指示的微胶囊型可视化传感器。以结晶紫内酯作为损伤指示剂,将其微胶囊化于聚甲基丙烯酸甲酯中以合成该传感器。通过傅里叶变换红外光谱法确认了成功的包封。通过改变搅拌速度获得了不同直径和尺寸分布的微胶囊。将制备的微胶囊嵌入聚合物涂层中以完成损伤指示。当涂层中出现裂缝时,无色形式的结晶紫内酯从破裂的微胶囊中释放出来。由于与混凝土中的二氧化硅发生反应,释放出的结晶紫内酯变成蓝色并突出显示受损区域。经证实,该传感器的可视化性能在干燥和潮湿条件下均具有良好的耐久性。所提出的微胶囊型可视化传感器具有易于制造、指示稳定性高和无需特殊设备要求等优点,这将显著降低混凝土结构健康监测的复杂性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9997/9047305/560b09e68368/c9ra09492j-f1.jpg

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