通过荧光“点击”反应对机械损伤进行定性传感。
Qualitative sensing of mechanical damage by a fluorogenic "click" reaction.
作者信息
Döhler Diana, Rana Sravendra, Rupp Harald, Bergmann Henrik, Behzadi Shahed, Crespy Daniel, Binder Wolfgang H
机构信息
Faculty of Natural Science II (Chemistry, Physics and Mathematics), Institute of Chemistry, Chair of Macromolecular Chemistry, Division of Technical and Macromolecular Chemistry, Martin Luther University Halle-Wittenberg, von-Danckelmann-Platz 4, Halle D-06120, Germany.
出版信息
Chem Commun (Camb). 2016 Sep 25;52(74):11076-9. doi: 10.1039/c6cc05390d. Epub 2016 Aug 19.
A simple and unique damage-sensing tool mediated by a Cu(i)-catalyzed [3+2] cycloaddition reaction is reported, where a fluorogenic "click"-reaction highlights physical damage by a strong fluorescence increase accompanied by in situ monitoring of localized self-healing.
报道了一种由铜（I）催化的[3+2]环加成反应介导的简单且独特的损伤传感工具，其中一种荧光“点击”反应通过强烈的荧光增强突出物理损伤，并伴有局部自修复的原位监测。
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