Yun Min Ju, Sim Yeon Hyang, Lee Dong Y, Cha Seung I
Energy Conversion Research Center, Electrical Materials Research Division, Korea Electrotechnology Research Institute Korea
Department of Electro-functionality Materials Engineering, University of Science and Technology Korea.
RSC Adv. 2020 Mar 26;10(21):12415-12422. doi: 10.1039/d0ra00439a. eCollection 2020 Mar 24.
Photovoltaic panels based on crystalline Si solar cells are the most widely utilized renewable source of electricity, and there has been a significant effort to produce panels with a higher energy conversion efficiency. Typically, these developments have focused on cell-level device modifications to restrict the recombination of photo-generated charge carriers, and concepts such as back surface field, passivated emitter and rear contact (PERC), interdigitated back contact, and heterojunction with intrinsic thin layer solar cells have been established. Here, we propose quasi-Fermi level control using periodic local focusing of incident light by encapsulation with polydimethylsiloxane to improve the performance of solar cells at the module-level; such improvements can complement cell-level enhancements. Locally focused incident light is used to modify the internal quasi-Fermi level of PERC solar cells owing to the localized photon distribution within the cell. Control of the local focusing conditions induces different quasi-Fermi levels, and therefore results in different efficiency changes. For example, central focusing between fingers enhances the current density with a reduced fill factor, whereas multiple local focusing enhances the fill factor rather than the current density. Here, these effects were explored for various angles of incidence, and the total electrical energy production was increased by 3.6% in comparison to a bare cell. This increase is significant as conventional ethylene vinyl acetate-based encapsulation reduces the efficiency as short-wavelength light is attenuated. However, this implies that additional module-scale studies are required to optimize local focusing methods and their synergy with device-level modifications to produce advanced photovoltaics.
基于晶体硅太阳能电池的光伏板是应用最广泛的可再生电源,人们一直在努力生产具有更高能量转换效率的光伏板。通常,这些进展集中在电池级器件的改进上,以限制光生电荷载流子的复合,诸如背表面场、钝化发射极及背接触(PERC)、叉指背接触和本征薄层异质结太阳能电池等概念已被确立。在此,我们提出通过用聚二甲基硅氧烷封装对入射光进行周期性局部聚焦来控制准费米能级,以提高太阳能电池在组件级的性能;这种改进可以补充电池级的增强效果。由于电池内光子的局部分布,局部聚焦的入射光被用于改变PERC太阳能电池的内部准费米能级。控制局部聚焦条件会导致不同的准费米能级,从而产生不同的效率变化。例如,指状电极间的中心聚焦会提高电流密度,但填充因子会降低,而多次局部聚焦会提高填充因子而非电流密度。在此,针对各种入射角探究了这些效应,与裸电池相比,总电能产量提高了3.6%。这一增长意义重大,因为传统的基于乙烯醋酸乙烯酯的封装会因短波长光的衰减而降低效率。然而,这意味着需要进行额外的组件级研究,以优化局部聚焦方法及其与器件级改进的协同作用,从而生产出先进的光伏产品。