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新型介孔Ag@SiO纳米球作为一种非均相催化剂,对芳香族硝基化合物的氢化反应具有优异的催化性能。

Novel mesoporous Ag@SiO nanospheres as a heterogeneous catalyst with superior catalytic performance for hydrogenation of aromatic nitro compounds.

作者信息

Li Wenyan, Lin Xinying, Long Jing, Zheng Bo, Pan Zhaorui, Lang Leiming, Liu Guangxiang

机构信息

Excellent Science and Technology Innovation Group of Jiangsu Province, Nanjing Xiaozhuang University Nanjing 211171 China

出版信息

RSC Adv. 2021 Nov 23;11(60):37708-37712. doi: 10.1039/d1ra06853a.

Abstract

Mesoporous core-shell structure Ag@SiO nanospheres are constructed to prevent Ag nanoparticles from aggregation during the hydrogenation reaction. The prepared catalyst shows superior catalytic performance for hydrogenation of nitro compounds with 100% conversion and selectivity without any by-products, which also indicates good recycling performance for several times use.

摘要

构建了介孔核壳结构的Ag@SiO纳米球,以防止银纳米颗粒在氢化反应过程中发生聚集。所制备的催化剂对硝基化合物的氢化反应表现出优异的催化性能,转化率和选择性均为100%,且无任何副产物,这也表明该催化剂在多次使用时具有良好的循环性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/06bc/9043839/93a9deba8923/d1ra06853a-s1.jpg

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