超越肖尔反应——通过机械化学实现纳米石墨烯的一步平面化和边缘氯化

Beyond the Scholl reaction - one-step planarization and edge chlorination of nanographenes by mechanochemistry.

作者信息

Baier Daniel M, Grätz Sven, Jahromi Babak Farhadi, Hellmann Sarah, Bergheim Konrad, Pickhardt Wilm, Schmid Rochus, Borchardt Lars

机构信息

Mechanochemistry Group, Faculty of Chemistry and Biochemistry, Ruhr-Universität Bochum Universitätsstraße 150 44780 Bochum Germany

Computational Materials Chemistry Group, Faculty for Chemistry and Biochemistry, Ruhr-Universität Bochum Universitätsstraße 150 44780 Bochum Germany.

出版信息

RSC Adv. 2021 Nov 25;11(60):38026-38032. doi: 10.1039/d1ra07679e. eCollection 2021 Nov 23.

The edge chlorination of the benchmark nanographenes triphenylene and hexa--hexabenzocoronene is conducted mechanochemically. This approach overcomes solubility limitations and eliminates the need for elaborate chlorination conditions. Additionally, the planarization of oligophenylenes and their edge-chlorination can be combined in a one-pot approach requiring as little as 60 minutes.