Organic template-based ZnO embedded MnO nanoparticles: synthesis and evaluation of their electrochemical properties towards clean energy generation.

To deal with fossil fuel depletion and the rise in global temperatures caused by fossil fuels, cheap and abundant materials are required, in order to fulfill energy demand by developing high-performance fuel cells and electrocatalysts. In this work, a natural organic agent has been used to synthesize nano-structured ZnO/MnO with high surface area and enhanced electrocatalytic performance. Upon pre-annealing treatment, mixed metal oxide precipitates are formed due to the complex formation between a metal oxide and organic extract. The thermally annealed mixed oxide ZnO/MnO was characterized by XRD diffractometer, Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX). Gas chromatography-mass spectrometry (GC-MS) identified methyldecylamine as a major stabilizing agent of the synthesized nanomaterial. Using a Tauc plot, the calculated band energy for the synthesized ZnO/MnO mixed metal oxide was 1.65 eV. Moreover, we have demonstrated the effects of incorporated organic compounds on the surface chemistry, morphology and electrochemical behavior of ZnO/MnO. The phyto-functionalized ZnO/MnO was deposited on Ni-foam for electrocatalytic studies. The fabricated electrode revealed good performance with low over-potential and Tafel slope, suggesting it to be suitable as a potential catalyst for water splitting application, in particular for the oxygen evolution reaction (OER). The overall findings of the current study provide a cost-effective and efficient organic template for functionalization and sustainable fabrication of ZnO/MnO nanomaterial for application as an electrocatalyst.