Electrospinning preparation and near-infrared absorption properties of a silica/cesium tungsten bronze micro-nano fiber membrane.

Silica/cesium tungsten bronze (SiO/Cs WO) composite micro-nano fiber membranes were prepared by the co-precursor electrostatic spinning method using cesium chloride, tungsten powder and tetraethyl orthosilicate as raw materials. TGA, XRD, FT-IR, XPS, SEM and ultraviolet-visible-near red spectrophotometry were used to analyze the thermal decomposition process, phase composition, microscopic morphology and near-infrared absorption properties of the product. Studies have shown that as the ratio of Cs/W of raw materials increases, the crystallinity of Cs WO in the product increases first and then decreases. When (Cs)/(W) reaches 0.5, its crystallinity is the most complete; similarly, calcination also contributes to the crystallization of CsWO, but high temperatures above 800 °C will also destroy its crystal structure. The study found that after calcination at 700 °C, the fiber membrane with a Cs/W atomic ratio of 0.5 has the best infrared absorption performance. The average absorbance of near-infrared light at 780-2500 nm is 1.5, which is 5.56 times that of the pure SiO fiber membrane. The tensile strength reaches 2.4 MPa, which can meet practical requirements. This research provides a basis for the development of flexible solar shading materials under complex outdoor conditions.