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新型可见光响应型铷汞碘纳米结构光催化剂的简便制备与表征

Facile preparation and characterization of a novel visible-light-responsive RbHgI nanostructure photocatalyst.

作者信息

Abkar Elham, Ghanbari Mojgan, Amiri Omid, Salavati-Niasari Masoud

机构信息

Institute of Nano Science and Nano Technology, University of Kashan P. O. Box. 87317-51167 Kashan Iran

Faculty of Chemistry, Razi University Kermanshah 6714414971 Iran.

出版信息

RSC Adv. 2021 Sep 16;11(49):30849-30859. doi: 10.1039/d1ra03152j. eCollection 2021 Sep 14.

Abstract

Visible photocatalytic procedures exhibit encouraging potential in water purification by increasing the photocatalytic performance. Therefore, the improvement of low-cost and efficient photocatalysts for environmental remediation is an increasing demand, and photocatalysts based on semiconductors have gained considerable attention due to their superior stability and activity. In the current study, novel RbHgI nanostructures were prepared a simple, low-cost, and low-temperature solid-state method. The effects of different parameters such as type of surfactants, reaction temperature, and reaction time were studied on the structure, crystallinity, particle size, and shape of nanostructures. This new compound has a suitable band gap (2.6 eV) in the visible region. The photocatalytic performance of RbHgI was examined for the removal of coloring agents under visible light irradiation and it was found that this compound could degrade and eliminate acid black 1 by about 72.1%.

摘要

可见的光催化过程通过提高光催化性能在水净化方面展现出令人鼓舞的潜力。因此,开发用于环境修复的低成本高效光催化剂的需求日益增加,基于半导体的光催化剂因其卓越的稳定性和活性而备受关注。在本研究中,采用简单、低成本且低温的固态方法制备了新型RbHgI纳米结构。研究了不同参数如表面活性剂类型、反应温度和反应时间对纳米结构的结构、结晶度、粒径和形状的影响。这种新化合物在可见光区域具有合适的带隙(2.6 eV)。研究了RbHgI在可见光照射下对去除着色剂的光催化性能,发现该化合物可降解并消除约72.1%的酸性黑1。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cda9/9041529/88543eb94c6f/d1ra03152j-s1.jpg

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