School of Metallurgy, Northeastern University, Shenyang, People's Republic of China.
Institute for Frontier Technologies of Low-Carbon Steelmaking, Northeastern University, Shenyang, People's Republic of China.
Environ Sci Pollut Res Int. 2022 Sep;29(43):65500-65520. doi: 10.1007/s11356-022-20420-w. Epub 2022 Apr 29.
In order to improve the recovery ratio of valuable metals in stainless steel dust, reduce environmental pollution, and promote solid waste resource recovery and sustainable development of industry, the synergistic reduction process for preparing Fe-Cr-Ni-C alloy was studied in detail by changing the addition of laterite nickel ore and reduction process conditions. The results show that with the addition of laterite nickel ore, the basicity of raw materials is reduced, the precipitation and aggregation of metal particles are promoted, the separation effect of metals and slags from reduction products is improved, and the metal recovery ratio also improved in the synergistic reduction process. When the ratio of stainless steel dust to laterite nickel ore is 94%:6%, reduction temperature is 1400 °C, reduction time is 20 min, and FC/O is 0.8, the metals and slags of the reduction product can be separated naturally after cooling; the recoveries of Fe, Cr, and Ni are 90.6%, 90.1%, and 91.2%, respectively. The grades of Fe, Cr, and Ni in the Fe-Cr-Ni-C alloy are 62.7%, 18.9%, and 4.1%, respectively. The content of harmful elements S and P in the alloy is low, so it can be directly used as raw material for stainless steel smelting.
为提高不锈钢粉尘中贵金属的回收率,减少环境污染,促进固体废物资源回收和工业可持续发展,通过改变添加红土镍矿和还原工艺条件,详细研究了制备 Fe-Cr-Ni-C 合金的协同还原过程。结果表明,随着红土镍矿的添加,原料的碱度降低,促进了金属颗粒的沉淀和聚集,提高了还原产物中金属和炉渣的分离效果,协同还原过程中的金属回收率也提高了。当不锈钢粉尘与红土镍矿的比例为 94%:6%、还原温度为 1400°C、还原时间为 20min、FC/O 为 0.8 时,还原产物的金属和炉渣在冷却后可自然分离;Fe、Cr 和 Ni 的回收率分别为 90.6%、90.1%和 91.2%。Fe-Cr-Ni-C 合金中 Fe、Cr 和 Ni 的品位分别为 62.7%、18.9%和 4.1%。合金中有害元素 S 和 P 的含量较低,可直接用作不锈钢冶炼的原料。