Huang Lingyu, Xie Rongrong, Wen Chaoying, Yang Yanyan, Wang Yiwen, Ren Shiyan, Huang Bin, Li Shiqing
Guangxi Key Laboratory of Electrochemical and Magneto-Chemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China.
Org Biomol Chem. 2022 May 18;20(19):3913-3916. doi: 10.1039/d2ob00500j.
A palladium-catalyzed decarbonylative/decarboxylative [4 + 2] annulation of phthalic anhydrides with cyclic diaryliodonium salts to synthesize triphenylenes has been developed. The reaction shows broad substrate scope with a high yield of up to 99%, and it provides an efficient and fast way to access functionalized triphenylenes in only one hour.
已开发出一种钯催化的邻苯二甲酸酐与环状二芳基碘鎓盐的脱羰基/脱羧[4 + 2]环化反应来合成三亚苯。该反应具有广泛的底物范围，产率高达99%，并且仅需一小时就能提供一种有效且快速的方法来获得功能化的三亚苯。
