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利用棉纤维-氧化石墨烯复合材料,采用间歇式和过滤吸附技术从水介质中去除有机污染物:一项对比研究。

Decontamination of organic pollutants from aqueous media using cotton fiber-graphene oxide composite, utilizing batch and filter adsorption techniques: a comparative study.

作者信息

Abd-Elhamid A I, Nayl A A, El Shanshory Ahmed A, Soliman Hesham M A, Aly H F

机构信息

Advanced Technology and New Materials Research Institute, City for Scientific Research and Technology Applications, SRTA P. O. Box 21934 Egypt.

Chemistry Department, College of Science, Jouf University Sakakah Saudi Arabia

出版信息

RSC Adv. 2019 Feb 18;9(10):5770-5785. doi: 10.1039/c8ra10449b. eCollection 2019 Feb 11.

Abstract

Cotton fiber-graphene oxide (C-GO) composite with high adsorptive properties towards the cationic dye, crystal violet (CV), was successfully fabricated by simple mixing of cotton fiber and GO in aqueous solution using a homogenizer. The as-prepared composite was characterized using TEM, SEM, LOM, XRD, FTIR, Raman and TGA. The characterization indicated that the formation of a homogeneous composite occurred adequate mixing of the cotton fiber and GO. The fine structure of the obtained composite was successfully used in two adsorption techniques, namely batch adsorption and filter adsorption. Various parameters affecting batch adsorption, such as contact time, dye concentration, composite dose, NaCl dose, temperature and pH were investigated. In the filter adsorption mode, dye concentration, composite dose, NaCl dose, temperature, flow rate and pH were studied. A comparison study between the two techniques, , batch adsorption and filter adsorption, are reported. The filter adsorption technique shows higher adsorption efficiency than the batch one, which was evident from the maximum adsorption capacity (°) values, obtained from the Langmuir isotherm. Further, the filter technique was developed and evaluated. This was achieved by regeneration, scaling-up and, finally, using another model of cationic dye (methylene blue).

摘要

通过使用均质器将棉纤维和氧化石墨烯(GO)在水溶液中简单混合,成功制备了对阳离子染料结晶紫(CV)具有高吸附性能的棉纤维-氧化石墨烯(C-GO)复合材料。使用透射电子显微镜(TEM)、扫描电子显微镜(SEM)、光学显微镜(LOM)、X射线衍射仪(XRD)、傅里叶变换红外光谱仪(FTIR)、拉曼光谱仪和热重分析仪(TGA)对所制备的复合材料进行了表征。表征结果表明,棉纤维和GO充分混合形成了均匀的复合材料。所获得的复合材料的精细结构成功应用于两种吸附技术,即分批吸附和过滤吸附。研究了影响分批吸附的各种参数,如接触时间、染料浓度、复合材料剂量、氯化钠剂量、温度和pH值。在过滤吸附模式下,研究了染料浓度、复合材料剂量、氯化钠剂量、温度、流速和pH值。报道了分批吸附和过滤吸附这两种技术之间的比较研究。过滤吸附技术显示出比分批吸附更高的吸附效率,这从朗缪尔等温线获得的最大吸附容量(°)值中可以明显看出。此外,对过滤技术进行了开发和评估。这是通过再生、放大,最后使用另一种阳离子染料模型(亚甲基蓝)来实现的。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e339/9060794/a889df8bb1e1/c8ra10449b-f1.jpg

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