Li Sheng-Jie, Chang Yong-Bin, Li Ming, Feng You-Xiang, Zhang Wen
MOE International Joint Laboratory of Materials Microstructure, Institute for New Energy Materials and Low Carbon Technologies, School of Material Science and Engineering, Tianjin University of Technology Tianjin 300384 China
RSC Adv. 2020 May 11;10(31):17951-17954. doi: 10.1039/c9ra10962e. eCollection 2020 May 10.
Herein, based on the strategy of synergetic catalysis, we report a cobalt-based coordination polymer PEI-Co. As a heterogeneous catalyst, PEI-Co shows a selectivity of 95% and a yield of 1170 mmol g for visible-light-driven CO-to-CO conversion in a water containing system, which is almost 2.8 times that of the mononuclear cobalt catalyst CoL and is comparable to that of the dinuclear cobalt catalyst CoL.
在此，基于协同催化策略，我们报道了一种钴基配位聚合物PEI-Co。作为一种多相催化剂，PEI-Co在含水体系中对可见光驱动的CO到CO₂转化显示出95%的选择性和1170 mmol g⁻¹的产率，这几乎是单核钴催化剂CoL的2.8倍，与双核钴催化剂CoL₂相当。
