Qi Yawei, Zhu Lifang, Gao Congjie, Shen Jiangnan
Center for Membrane Separation and Water Science & Technology, Ocean College, Zhejiang University of Technology Hangzhou 310014 P. R. China
Zhejiang University of Water Resources and Electric Power Hangzhou 310018 P. R. China.
RSC Adv. 2019 Feb 19;9(11):6107-6117. doi: 10.1039/c8ra09875a. eCollection 2019 Feb 18.
A novel nanofiltration membrane prepared by modification of a commercial membrane surface is fabricated using polydopamine (PDA) and hydroxyl propyl trimethyl ammonium chloride chitosan (HACC) mixed with chitosan (CN) and chelated silver (Ag) nanoparticles. The surface chemical composition, cross-sectional morphology, hydrophilicity and surface structure of the prepared membranes were examined by scanning electron microscopy, water contact angle measurements, and atomic force microscopy, respectively. The membrane performance was evaluated in terms of volumetric flux and protein rejection. In addition, the antifouling and antibacterial properties of the membranes were also explored. The results demonstrated that the prepared membranes exhibited an excellent antifouling property due to their three-layer architecture and it provided a special layer to promote the antibacterial property. According to the results, the modified membrane has a significantly improved flux recovery rate (over 96%). Besides, the antibacterial activity tests showed that the proposed three-layer architecture modification extensively prevented bacterial growth on the membrane surface.
一种通过对商用膜表面进行改性制备的新型纳滤膜,是利用聚多巴胺(PDA)、羟丙基三甲基氯化铵壳聚糖(HACC)与壳聚糖(CN)混合,并螯合银(Ag)纳米颗粒制成的。分别通过扫描电子显微镜、水接触角测量和原子力显微镜对制备膜的表面化学成分、横截面形态、亲水性和表面结构进行了检测。从体积通量和蛋白质截留率方面对膜性能进行了评估。此外,还探究了膜的抗污染和抗菌性能。结果表明,制备的膜由于其三层结构而表现出优异的抗污染性能,并且它提供了一个特殊层来促进抗菌性能。根据结果,改性膜的通量回收率显著提高(超过96%)。此外,抗菌活性测试表明,所提出的三层结构改性广泛地阻止了细菌在膜表面的生长。