硅基框架中封装良好的多金属氧酸盐离子液体用于烯烃的环境友好型不对称二羟基化反应
Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins.
作者信息
Liang Dong, Wang Yan, Wang Sifan, Song Chengkun, Shi Yonghe, Liu Qinghao, Zhu Hailin, Li Xia, Liu Laishuan, Zhu Na
机构信息
School of Chemical Engineering and Technology, North University of China Taiyuan People's Republic of China 030051
College of Chemistry and Chemical Engineering, Taiyuan University of Technology Taiyuan People's Republic of China 030024.
出版信息
RSC Adv. 2019 Feb 19;9(11):6102-6106. doi: 10.1039/c8ra10544h. eCollection 2019 Feb 18.
Chiral 1,2-diols with a high yield could be directly prepared from asymmetric di-hydroxylation of olefins an eco-friendly and enduring catalyst, in which abundant "chiral pools" of polyoxometalate-ionic liquid were target-designed into the silicic framework (POM-ILS) and well stabilized in aqueous media.
手性1,2 -二醇可以通过烯烃的不对称双羟基化反应直接高产率制备，使用一种环保且持久的催化剂，其中多金属氧酸盐 - 离子液体丰富的“手性库”被靶向设计到硅框架（POM - ILS）中，并在水性介质中得到良好稳定。
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