决定双（硫代氨基脲）铜（II）配合物中硫酮（硫醇）-二硫键相互转化的因素。

Factors that determine thione(thiol)-disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex.

作者信息

Jeong Haewon, Kang Yeji, Kim Jin, Kim Byung-Kwon, Hong Seungwoo

机构信息

Department of Chemistry, Sookmyung Women's University Seoul 04310 Korea

Western Seoul Centre, Korea Basic Science Institute Seoul 03759 Republic of Korea.

出版信息

RSC Adv. 2019 Mar 19;9(16):9049-9052. doi: 10.1039/c9ra01115c. eCollection 2019 Mar 15.

Solvent-, acidity-, and redox-responsive thione(thiol)-disulfide interconversion were achieved by a dinuclear copper(ii) complex bearing a bis(thiosemicarbazone) (bTSC) ligand. The role of copper(ii) ion coordination was rationalized by parallel comparison with a bare bTSC ligand and zinc(ii) bTSC complexes under identical reaction conditions.