二硫键交换：通过动态共价化学揭示超分子反应性。
Disulfide exchange: exposing supramolecular reactivity through dynamic covalent chemistry.
机构信息
University Chemical Laboratory, University of Cambridge, Lensfield Road, Cambridge, UKCB21EW.
出版信息
Chem Soc Rev. 2014 Mar 21;43(6):1861-72. doi: 10.1039/c3cs60326a.
PMID:24132207
Abstract
A Tutorial Review of the subtle supramolecular interactions influencing the outcomes of equilibrating systems, focusing on the dynamic covalent chemistry (DCC) of disulfide exchange reactions, is presented. We discuss the topics of cation-π interactions (2.1), hydrophobic effects (2.2), hydrogen bonding interactions (2.3) aromatic donor-acceptor interactions (2.4), and metal-ligand interactions (2.5) in the context of dynamic disulfide chemistry.
摘要
本文综述了影响平衡体系结果的微妙超分子相互作用，重点介绍了二硫交换反应的动态共价化学（DCC）。我们讨论了阳离子-π 相互作用（2.1）、疏水效应（2.2）、氢键相互作用（2.3）、芳香供体-受体相互作用（2.4）和金属-配体相互作用（2.5）在动态二硫键化学中的作用。
Zotero 插件