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低温条件对锂离子电池的影响及一种绝缘材料的应用

Influence of low temperature conditions on lithium-ion batteries and the application of an insulation material.

作者信息

Ouyang Dongxu, He Yaping, Weng Jingwen, Liu Jiahao, Chen Mingyi, Wang Jian

机构信息

State Key Laboratory of Fire Science, University of Science and Technology of China Hefei 230026 China

School of Computing, Engineering and Mathematics, Western Sydney University Sydney 1797 Australia.

出版信息

RSC Adv. 2019 Mar 19;9(16):9053-9066. doi: 10.1039/c9ra00490d. eCollection 2019 Mar 15.

Abstract

In the current work, a series of experiments were carried out under low and normal temperature conditions (0 and 20 °C) to research the influence of low temperature on the performance of lithium-ion batteries (LIBs). Besides this, a commercial insulation material (IM) was employed to research its effect on preventing damage in a battery exposed to low temperature. Based on the experimental results, it was found that the battery exhibited a higher temperature increase at low ambient temperature due to the larger internal resistance of the battery at low temperature, which resulted in greater heat generation. It was also observed that the low temperature caused the uniformity of the battery to deteriorate as a result of temperature and voltage differences, and the uniformity became poorer with increasing cycle rate. Moreover, the capacity decay rate of the battery was demonstrated to be greatly accelerated by the low temperature. According to the morphological changes of the battery components, the structure of the electrode materials and separator was damaged under low temperature conditions. Finally, the results show that the IM had a significant effect on warming the battery up; therefore, a much better discharge performance and slower decay rate of the battery were achieved. Furthermore, the performance of the IM was found to be related to its thickness.

摘要

在当前工作中,在低温和常温条件(0和20°C)下进行了一系列实验,以研究低温对锂离子电池(LIBs)性能的影响。除此之外,使用了一种商用绝缘材料(IM)来研究其对暴露于低温下的电池防止损坏的效果。基于实验结果发现,由于电池在低温下具有较大的内阻,导致产生更多热量,电池在低环境温度下表现出更高的温度升高。还观察到,由于温度和电压差异,低温导致电池的均匀性变差,并且随着循环速率的增加均匀性变得更差。此外,低温被证明极大地加速了电池的容量衰减率。根据电池组件的形态变化,电极材料和隔膜的结构在低温条件下受到损坏。最后,结果表明IM对电池升温有显著效果;因此,实现了更好的放电性能和更慢的电池衰减率。此外,发现IM的性能与其厚度有关。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2355/9062004/300ff07915e7/c9ra00490d-f1.jpg

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