Palaniappan N, Cole I S, Caballero-Briones F, Manickam S, Lal C, Sathiskumar J
School of Chemical Sciences, Central University of Gujarat 382030 India
Advance Manufacturing and Fabrication Research and Innovation, RMIT University Melbourne Vic 3100 Australia.
RSC Adv. 2019 Mar 14;9(15):8537-8545. doi: 10.1039/c9ra00106a. eCollection 2019 Mar 12.
Ti6Al4V alloy is light weight and is used in construction, oil industries and airbus, automobile, and bio implant materials. The native oxide layers of the alloy are not stable at high temperatures and strong mineral acid environments. The conventional epoxy-based layers are porous and the alloy finally fails in the harsh environment in the long term. Therefore, the carbon-based functional materials are being proposed as coating materials to overcome the alloy degradation. In the present contribution, we have used the neodymium-decorated graphene oxide as the corrosion inhibiting barrier for the Ti6Al4V alloy. As a novelty, we found that the few-layer graphene decorated with neodymium acts as a self-cleaning coating. The Nd-decorated graphene oxide were studied by XRD, TEM, FESEM, FTIR, UV, and Raman spectroscopy. The corrosion inhibition efficiency was studied by electrochemical methods.
Ti6Al4V合金重量轻,用于建筑、石油工业以及空中客车、汽车和生物植入材料。该合金的原生氧化层在高温和强无机酸环境下不稳定。传统的环氧基层是多孔的,合金最终会在长期的恶劣环境中失效。因此,人们提出将碳基功能材料作为涂层材料来克服合金的降解问题。在本研究中,我们使用钕修饰的氧化石墨烯作为Ti6Al4V合金的缓蚀屏障。新颖的是,我们发现钕修饰的少层石墨烯可作为自清洁涂层。通过X射线衍射、透射电子显微镜、场发射扫描电子显微镜、傅里叶变换红外光谱、紫外光谱和拉曼光谱对钕修饰的氧化石墨烯进行了研究。通过电化学方法研究了缓蚀效率。