分级TS-1封装的亚纳米Pd/PdO杂化物上高效过氧化氢直接合成
Highly efficient hydrogen peroxide direct synthesis over a hierarchical TS-1 encapsulated subnano Pd/PdO hybrid.
作者信息
Lyu Jinghui, Wei Jun, Niu Lei, Lu Chunshan, Hu Yiwei, Xiang Yizhi, Zhang Guofu, Zhang Qunfeng, Ding Chengrong, Li Xiaonian
机构信息
College of Chemical Engineering, Zhejiang University of Technology Hangzhou 310032 People's Republic of China
Dave C. Swalm School of Chemical Engineering, Mississippi State University Mississippi 39762 USA.
出版信息
RSC Adv. 2019 Apr 30;9(24):13398-13402. doi: 10.1039/c9ra02452b.
We report a hierarchical TS-1 encapsulated subnano Pd/PdO hybrid catalyst that shows unprecedented activity in HO direct synthesis from H and O. The macro reaction rate in 30 min is up to 35 010 mmol g h at ambient temperature. Such high catalytic activity is achieved due to the hierarchical porous structure of TS-1 and the formation of the encapsulated subnano Pd/PdO hybrid after oxidation/reduction/oxidation treatment.
我们报道了一种分级结构的TS-1封装亚纳米Pd/PdO混合催化剂，该催化剂在由H₂和O₂直接合成H₂O方面表现出前所未有的活性。在环境温度下，30分钟内的宏观反应速率高达35010 mmol g⁻¹ h⁻¹。如此高的催化活性归因于TS-1的分级多孔结构以及经过氧化/还原/氧化处理后形成的封装亚纳米Pd/PdO混合物。
Zotero 插件