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具有高吸附能力的磷酸化碳纳米纤维在从地下水中螯合铀方面的前瞻性应用。

Prospective application of phosphorylated carbon nanofibers with a high adsorption capacity for the sequestration of uranium from ground water.

作者信息

Dhanya V, Arunraj Balasubramanian, Rajesh N

机构信息

Department of Chemistry, Birla Institute of Technology and Science, Pilani Hyderabad Campus, Jawahar Nagar Hyderabad 500078 India

出版信息

RSC Adv. 2022 May 4;12(21):13511-13522. doi: 10.1039/d2ra02031a. eCollection 2022 Apr 28.

Abstract

In this study carbon nanofibers (CNF) were phosphorylated by using -phosphoric acid and applied for adsorptive remediation of uranium from water. The phosphorylated carbon nanofibers (PCNF) showed 96% removal of uranium as compared to 79% by CNF. The adsorption data from batch adsorption studies fitted well with the Langmuir model and a maximum adsorption capacity of 512.8 mg g was obtained at pH 6.0 while the adsorption followed pseudo second order kinetics. A detailed characterisation of the adsorbent has been carried out using various analytical and spectroscopic tools. The application of the adsorbent to ground water samples exhibited promising results even in the presence of other interfering cations and anions which is imperative considering the toxic effects of uranium in ground water.

摘要

在本研究中,使用磷酸对碳纳米纤维(CNF)进行磷酸化处理,并将其用于从水中吸附修复铀。与CNF对铀79%的去除率相比,磷酸化碳纳米纤维(PCNF)对铀的去除率为96%。批量吸附研究的吸附数据与朗缪尔模型拟合良好,在pH 6.0时获得的最大吸附容量为512.8 mg/g,且吸附遵循准二级动力学。已使用各种分析和光谱工具对吸附剂进行了详细表征。即使存在其他干扰阳离子和阴离子,该吸附剂应用于地下水样品时仍显示出良好的效果,考虑到铀在地下水中的毒性影响,这一点至关重要。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b959/9066443/19b3fe734aa3/d2ra02031a-f1.jpg

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