Dhanya V, Rajesh N
Department of Chemistry, Birla Institute of Technology and Science, Pilani Hyderabad Campus, Jawahar Nagar Hyderabad 500078 India
RSC Adv. 2023 Feb 1;13(7):4394-4406. doi: 10.1039/d2ra08333g. eCollection 2023 Jan 31.
Sustainable materials for remediation of pollutants from water is the need of the hour. In this study two carbonaceous adsorbents prepared through hydrothermal carbonisation and pyrolysis from arecanut husk fiber, an agricultural waste material were used for the adsorption of uranium from water. Batch adsorption data as interpreted using the Langmuir model showed adsorption capacities of 250 mg g and 200 mg g respectively at pH 6 for the hydrochar (AHFC) and the pyrochar (AHFT) exceeding that reported for most of the unmodified biochars. The adsorption followed pseudo-second order kinetics and was exothermic in nature. The high selectivity and excellent removal efficiencies on application to environmental ground water samples and good regeneration capacity make these sorbents promising eco-friendly materials for uranium remediation from water.
采用可持续材料从水中去除污染物是当务之急。在本研究中,通过水热碳化和热解由农业废料槟榔壳纤维制备的两种碳质吸附剂,用于从水中吸附铀。使用朗缪尔模型解释的批量吸附数据表明,在pH值为6时,水热炭(AHFC)和热解炭(AHFT)的吸附容量分别为250 mg/g和200 mg/g,超过了大多数未改性生物炭的报道值。吸附遵循准二级动力学,本质上是放热的。这些吸附剂在应用于环境地下水样品时具有高选择性和优异的去除效率,并且具有良好的再生能力,使其成为从水中修复铀的有前景的环保材料。