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基于樱花的活性炭制备及其在超级电容器应用中的性能

Sakura-based activated carbon preparation and its performance in supercapacitor applications.

作者信息

Ma Fei, Ding Shaolan, Ren Huijun, Liu Yanhua

机构信息

College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology Xi'an 710021 China

School of Arts and Sciences of Shaanxi University of Science & Technology Xi'an 710021 China.

出版信息

RSC Adv. 2019 Jan 18;9(5):2474-2483. doi: 10.1039/c8ra09685f.

Abstract

3D porous carbonaceous materials were prepared by combining pre-carbonization and KOH activation with sakura petals as raw materials. The prepared porous sakura carbon (SAC-4) exhibits a high specific surface area, a suitable pore size distribution, a low proportion of oxygen-rich groups and N functional groups, and a partially graphitized phase, which are very beneficial for the electrochemical performance of the material as a supercapacitor electrode. In the activation step, when the mass ratio of KOH to sakura carbon (SC) is 4, a supercapacitor is prepared. A maximal specific capacitance of 265.8 F g is obtained when the current density is 0.2 A g. When the current density is 1 A g, after 2000 cycles in succession, the capacitance retention rate is excellent and the cycling stability can reach as high as 90.2%. The obtained results indicate that porous carbon prepared with sakura blossom as the raw material is an effective and environmentally friendly electrode material for energy storage.

摘要

以樱花花瓣为原料,通过预碳化和KOH活化相结合的方法制备了3D多孔碳质材料。制备的多孔樱花碳(SAC-4)具有高比表面积、合适的孔径分布、低比例的富氧基团和N官能团以及部分石墨化相,这些对于该材料作为超级电容器电极的电化学性能非常有利。在活化步骤中,当KOH与樱花碳(SC)的质量比为4时,制备了一种超级电容器。当电流密度为0.2 A g时,获得的最大比电容为265.8 F g 。当电流密度为1 A g时,连续循环2000次后,电容保持率优异,循环稳定性高达90.2%。所得结果表明,以樱花为原料制备的多孔碳是一种有效且环保的储能电极材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2353/9059875/ca78be97481d/c8ra09685f-f1.jpg

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