Key laboratory of Bio-based Material Science and Technology, Ministry of Education, Northeast Forestry University, Harbin 150040, P. R. China.
Department of Energy Engineering, School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798, South Korea.
Chem Soc Rev. 2018 Apr 23;47(8):2837-2872. doi: 10.1039/C7CS00790F.
Nanocellulose has emerged as a sustainable and promising nanomaterial owing to its unique structures, superb properties, and natural abundance. Here, we present a comprehensive review of the current research activities that center on the development of nanocellulose for advanced electrochemical energy storage. We begin with a brief introduction of the structural features of cellulose nanofibers within the cell walls of cellulose resources. We then focus on a variety of processes that have been explored to fabricate nanocellulose with various structures and surface chemical properties. Next, we highlight a number of energy storage systems that utilize nanocellulose-derived materials, including supercapacitors, lithium-ion batteries, lithium-sulfur batteries, and sodium-ion batteries. In this section, the main focus is on the integration of nanocellulose with other active materials, developing films/aerogel as flexible substrates, and the pyrolyzation of nanocellulose to carbon materials and their functionalization by activation, heteroatom-doping, and hybridization with other active materials. Finally, we present our perspectives on several issues that need further exploration in this active research field in the future.
纳米纤维素因其独特的结构、卓越的性能和丰富的天然资源而成为一种有前途的可持续纳米材料。在这里,我们全面回顾了当前以开发用于先进电化学储能的纳米纤维素为中心的研究活动。我们首先简要介绍了纤维素纳米纤维在纤维素资源细胞壁中的结构特征。然后,我们专注于各种已经探索过的工艺,以制造具有各种结构和表面化学性质的纳米纤维素。接下来,我们重点介绍了一些利用纳米纤维素衍生材料的储能系统,包括超级电容器、锂离子电池、锂硫电池和钠离子电池。在这一部分,主要重点是纳米纤维素与其他活性材料的整合,开发薄膜/气凝胶作为柔性基板,以及纳米纤维素的热解为碳材料及其通过活化、杂原子掺杂和与其他活性材料的杂交进行功能化。最后,我们提出了我们对未来这个活跃研究领域中需要进一步探索的几个问题的看法。