Liu Runlu, Chen Zhixin, Yao Yao, Li Yao, Cheema Waqas A, Wang Dawei, Zhu Shenmin
State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University Shanghai 200240 China
School of Mechanical, Materials, Mechatronics and Biomedical Engineering, University of Wollongong Wollongong 2522 Australia.
RSC Adv. 2020 Aug 11;10(49):29408-29418. doi: 10.1039/d0ra05779g. eCollection 2020 Aug 5.
Carbon dioxide (CO) is a very important micro-molecular resource. Using CO captured from the atmosphere for high-output synthesis of chemicals as raw materials has great significance and potential for various industrial applications. Since the industrial revolution in the 18 century, manmade CO emission has increased by 45%, which negatively impacts the planetary climate by the so-called greenhouse effect. Therefore, high-efficiency photocatalysis and photocatalysts for CO conversion have become the most important challenges and milestones throughout the world. In consideration of this, various catalysts have been explored. Among these, graphitic carbon nitride (g-CN) as a semiconductor is emerging as a highly promising photocatalyst for removing CO from the atmosphere. Moreover, due to its excellent chemical stability and unique band structure, g-CN has exhibited significant application potential for photocatalysis. This review summarizes the advancements that have been made in the synthesis and photocatalytic applications of g-CN-based catalysts for CO reduction in recent years and explains the future challenges and prospects in this vital area of research.
二氧化碳(CO₂)是一种非常重要的微观分子资源。利用从大气中捕获的二氧化碳作为原料进行高产量化学品合成,对各种工业应用具有重大意义和潜力。自18世纪工业革命以来,人为二氧化碳排放量增加了45%,通过所谓的温室效应给地球气候带来负面影响。因此,用于二氧化碳转化的高效光催化和光催化剂已成为全球最重要的挑战和里程碑。考虑到这一点,人们探索了各种催化剂。其中,作为半导体的石墨相氮化碳(g-C₃N₄)正成为一种极具前景的用于从大气中去除二氧化碳的光催化剂。此外,由于其优异的化学稳定性和独特的能带结构,g-C₃N₄在光催化方面展现出了巨大的应用潜力。本综述总结了近年来基于g-C₃N₄的催化剂在二氧化碳还原合成及光催化应用方面取得的进展,并阐述了这一重要研究领域未来面临的挑战和前景。