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揭示石墨相氮化碳(g-CN)的光催化潜力:最新综述

Unveiling the photocatalytic potential of graphitic carbon nitride (g-CN): a state-of-the-art review.

作者信息

Ahmed Mahmoud A, Mahmoud Safwat A, Mohamed Ashraf A

机构信息

Chemistry Department, Faculty of Science, Ain Shams University Cairo-11566 Egypt

Physics Department, Faculty of Science, Northern Border University Arar 13211 Saudi Arabia.

出版信息

RSC Adv. 2024 Aug 15;14(35):25629-25662. doi: 10.1039/d4ra04234d. eCollection 2024 Aug 12.

Abstract

Graphitic carbon nitride (g-CN)-based materials have emerged as promising photocatalysts due to their unique band structure, excellent stability, and environmental friendliness. This review provides a comprehensive and in-depth analysis of the current state of research on g-CN-based photocatalysts. The review summarizes several strategies to improve the photocatalytic performance of pristine g-CN, , by creating heterojunctions, doping with non-metallic and metallic materials, co-catalyst loading, tuning catalyst morphology, metal deposition, and nitrogen-defect engineering. The review also highlights the various characterization techniques employed to elucidate the structural and physicochemical features of g-CN-based catalysts, as well as their applications of in photocatalytic degradation and hydrogen production, emphasizing their remarkable performance in pollutants' removal and clean energy generation. Furthermore, this review article investigates the effect of operational parameters on the catalytic activity and efficiency of g-CN-based catalysts, shedding light on the key factors that influence their performance. The review also provides insights into the photocatalytic pathways and reaction mechanisms involving g-CN based photocatalysts. The review also identifies the research gaps and challenges in the field and presents prospects for the development and utilization of g-CN-based photocatalysts. Overall, this comprehensive review provides valuable insights into the synthesis, characterization, applications, and prospects of g-CN-based photocatalysts, offering guidance for future research and technological advancements in this rapidly growing field.

摘要

基于石墨相氮化碳(g-CN)的材料因其独特的能带结构、优异的稳定性和环境友好性,已成为有前景的光催化剂。本文综述对基于g-CN的光催化剂的当前研究状况进行了全面而深入的分析。该综述总结了几种提高原始g-CN光催化性能的策略,包括创建异质结、用非金属和金属材料掺杂、负载助催化剂、调整催化剂形态、金属沉积和氮缺陷工程。该综述还重点介绍了用于阐明基于g-CN的催化剂的结构和物理化学特征的各种表征技术,以及它们在光催化降解和制氢方面的应用,强调了它们在去除污染物和产生清洁能源方面的卓越性能。此外,这篇综述文章研究了操作参数对基于g-CN的催化剂的催化活性和效率的影响,揭示了影响其性能的关键因素。该综述还深入探讨了涉及基于g-CN的光催化剂的光催化途径和反应机制。该综述还确定了该领域的研究差距和挑战,并提出了基于g-CN的光催化剂的开发和利用前景。总体而言,这篇全面的综述为基于g-CN的光催化剂的合成、表征、应用和前景提供了有价值的见解,为这个快速发展的领域的未来研究和技术进步提供了指导。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6907/11325859/8585790399f2/d4ra04234d-f1.jpg

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