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使用一种新的轴对称液滴/气泡形状技术进行界面张力测量。

Interfacial tension measurements using a new axisymmetric drop/bubble shape technique.

作者信息

Cabrerizo-Vilchez M A, Fernández J R, Fernández-Rodríguez M A, García-Río L, Muñiz M C, Núñez Cristina

机构信息

Biocolloid and Fluid Physics Group, Applied Physics Department, Faculty of Sciences, University of Granada Avda. de la Fuente Nueva s/n E-18071 Granada Spain.

Department of Applied Mathematics I, University of Vigo Campus Universitario As Lagoas Marcosende s/n E-36310 Vigo Spain.

出版信息

RSC Adv. 2019 May 23;9(28):16187-16194. doi: 10.1039/c9ra00940j. eCollection 2019 May 20.

DOI:10.1039/c9ra00940j
PMID:35521365
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9064388/
Abstract

This paper introduces a new mathematical model that is used to compute either the interfacial tension of quiescent axisymmetric pendant/sessile drops and pendant/captive bubbles. This model consists of the Young-Laplace equation, that describes interface shape, together with suitable boundary conditions that guarantee a prescribed volume of drops/bubbles and a fixed position in the capillary. In order to solve the problem numerically, the Young-Laplace equation is discretized by using numerical differentiation and the numerical solutions are obtained applying the well-know Newton method. The paper contains a validation of the new methodology presented for what theoretical bubble/drops are used. Finally, some numerical results are presented for both drops and bubbles of water as well as several surfactant solutions to demonstrate the applicability, versatility and reproducibility of the proposed methodology.

摘要

本文介绍了一种新的数学模型,该模型用于计算静态轴对称悬垂/ sessile液滴以及悬垂/俘获气泡的界面张力。该模型由描述界面形状的杨-拉普拉斯方程以及合适的边界条件组成,这些边界条件可确保液滴/气泡的规定体积以及在毛细管中的固定位置。为了对该问题进行数值求解,通过数值微分对杨-拉普拉斯方程进行离散化,并应用著名的牛顿法获得数值解。本文针对所使用的理论气泡/液滴对提出的新方法进行了验证。最后,给出了水以及几种表面活性剂溶液的液滴和气泡的一些数值结果,以证明所提出方法的适用性、通用性和可重复性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a13/9064388/7502fc5f60b5/c9ra00940j-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a13/9064388/302cf4cd5ac5/c9ra00940j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a13/9064388/6179c26362ef/c9ra00940j-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a13/9064388/02240d7a75f3/c9ra00940j-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a13/9064388/6b8ece4bc973/c9ra00940j-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a13/9064388/c0a68082842e/c9ra00940j-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a13/9064388/41774d6a94bf/c9ra00940j-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a13/9064388/7502fc5f60b5/c9ra00940j-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a13/9064388/302cf4cd5ac5/c9ra00940j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a13/9064388/6179c26362ef/c9ra00940j-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a13/9064388/02240d7a75f3/c9ra00940j-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a13/9064388/6b8ece4bc973/c9ra00940j-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a13/9064388/c0a68082842e/c9ra00940j-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a13/9064388/41774d6a94bf/c9ra00940j-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a13/9064388/7502fc5f60b5/c9ra00940j-f7.jpg

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本文引用的文献

1
Axisymmetric Drop Shape Analysis (ADSA): An Outline.轴对称液滴形状分析(ADSA):概述。
Adv Colloid Interface Sci. 2016 Dec;238:62-87. doi: 10.1016/j.cis.2016.11.001. Epub 2016 Nov 6.
2
The science of foaming.泡沫科学。
Adv Colloid Interface Sci. 2015 Aug;222:228-59. doi: 10.1016/j.cis.2015.04.001. Epub 2015 Apr 18.
3
Total Gaussian curvature, drop shapes and the range of applicability of drop shape techniques.总高斯曲率、液滴形状和液滴形状技术的适用范围。
Adv Colloid Interface Sci. 2014 Feb;204:1-14. doi: 10.1016/j.cis.2013.12.001. Epub 2013 Dec 14.
4
Simultaneous measurement of contact angle and surface tension using axisymmetric drop-shape analysis-no apex (ADSA-NA).使用轴对称滴形分析-无顶点法(ADSA-NA)同时测量接触角和表面张力。
Langmuir. 2011 Apr 5;27(7):3485-95. doi: 10.1021/la104155x. Epub 2011 Feb 28.
5
Mixed DPPC/DPPG monolayers at very high film compression.在非常高的薄膜压缩条件下的混合二棕榈酰磷脂酰胆碱/二棕榈酰磷脂酰甘油单分子层。
Langmuir. 2009 Sep 15;25(18):10907-12. doi: 10.1021/la901250z.
6
Recent progress in axisymmetric drop shape analysis (ADSA).轴对称液滴形状分析(ADSA)的最新进展。
Adv Colloid Interface Sci. 2006 Sep 13;121(1-3):25-49. doi: 10.1016/j.cis.2006.06.001. Epub 2006 Jul 18.
7
A finite element based algorithm for determining interfacial tension (gamma) from pendant drop profiles.一种基于有限元的从悬滴轮廓确定界面张力(γ)的算法。
J Colloid Interface Sci. 2005 Jun 15;286(2):647-60. doi: 10.1016/j.jcis.2005.01.052.
8
Axisymmetric Drop Shape Analysis: Computational Methods for the Measurement of Interfacial Properties from the Shape and Dimensions of Pendant and Sessile Drops.轴对称液滴形状分析:通过悬滴和 sessile 液滴的形状及尺寸测量界面性质的计算方法
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