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具有跨越红色和近红外区域双峰发射的固态发光O-硼二吡咯染料。

Solid-state emissive O-BODIPY dyes with bimodal emissions across red and near infrared region.

作者信息

El-Ali H A Abdulhadi, Jing Jing, Zhang Xiaoling

机构信息

Key Laboratory of Cluster Science of Ministry of Education, Beijing Key Laboratory of Photo-electronic/Electro-photonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology Beijing 100081 P. R. China.

College of Agriculture, Al-Muthanna University Samawah Al-Muthanna Province Iraq.

出版信息

RSC Adv. 2019 May 23;9(28):16246-16251. doi: 10.1039/c8ra10296a. eCollection 2019 May 20.

Abstract

Fluorescent compounds with solid-state emission are expected to have broad applications in the development of optoelectronic devices. In this study, we develop O-BODIPY based fluorescent dyes which exhibit strong bimodal solid-state emissions across red and NIR regions. After one pot synthesis, samples are characterized by X-ray diffraction, cyclic voltammetry, UV-vis absorption, and fluorescence spectra. All the experimental data reveal the multiple excitation and efficient emission features in the aggregation states. Furthermore, the two produced probes can be successfully applied for tracking lysosomes in HeLa cells with low cytotoxicity.

摘要

具有固态发射的荧光化合物有望在光电器件的开发中得到广泛应用。在本研究中,我们开发了基于O-硼二吡咯的荧光染料,其在红色和近红外区域表现出强烈的双峰固态发射。经过一锅法合成后,通过X射线衍射、循环伏安法、紫外可见吸收光谱和荧光光谱对样品进行了表征。所有实验数据都揭示了聚集态下的多重激发和高效发射特性。此外,所制备的两种探针能够成功应用于低细胞毒性的HeLa细胞溶酶体追踪。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e0fe/9064346/64af61957b6f/c8ra10296a-s1.jpg

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