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基于掺镍 TiO 的高级氧化工艺提高废水中抗生素污染物的光降解性能

Improved photodegradation of antibiotics pollutants in wastewaters by advanced oxidation process based on Ni-doped TiO.

机构信息

Department of Science and Technology and International Affairs, HUTECH University, 475A Dien Bien Phu Street, Ward 25, Binh Thanh District, Ho Chi Minh City, 700000, Viet Nam.

Department of Materials Science and Engineering, Gachon University, 1342 Seongnam-daero, Sujeong-gu, Seongnam, 13120, South Korea.

出版信息

Chemosphere. 2022 Sep;302:134837. doi: 10.1016/j.chemosphere.2022.134837. Epub 2022 May 4.

Abstract

The number of antibiotic compounds in wastewaters has been growing globally due to the covid-19 problem. Using antibiotics to treat the patients would produce larger amounts of these compounds into the environment with negative impacts. Hence, finding out the method for the elimination of toxic organic pollutants as well as antibiotics in water is urgent (In this study, the treatment of antibiotic pollutants including cefalexin (CF) and tetracycline (TC) was investigated by applying the advanced oxidation process based on Ni-doped TiO (Ni-TiO). The characterizations technologies such as XRD, XPS, UV-vis, PL, and PC indicated that Ni doping would improve the photocatalytic performance of TiO. In the photodegradation experiments, the Ni-TiO possessed high photocatalytic degradation efficiencies with 93.6% for CF and 82.5% for TC. Besides, the removal rates of antibiotics after five cycles are higher than 75%, implying excellent stability of Ni-TiO photocatalyst. The result from the treatment of wastewater samples revealed that the Ni-TiO photocatalytic had good performance for removal of CF and TC at a high level of 88.6 and 80.2%, respectively.

摘要

由于新冠疫情问题,全球废水中的抗生素化合物数量一直在增加。用抗生素治疗病人会导致这些化合物大量进入环境,产生负面影响。因此,寻找一种方法来消除水中的有毒有机污染物和抗生素是紧迫的(在这项研究中,通过应用基于 Ni 掺杂 TiO(Ni-TiO)的高级氧化工艺来处理包括头孢氨苄(CF)和四环素(TC)在内的抗生素污染物。XRD、XPS、UV-vis、PL 和 PC 等表征技术表明,Ni 掺杂会提高 TiO 的光催化性能。在光降解实验中,Ni-TiO 具有很高的光催化降解效率,对 CF 的降解效率为 93.6%,对 TC 的降解效率为 82.5%。此外,经过五次循环后,抗生素的去除率高于 75%,表明 Ni-TiO 光催化剂具有优异的稳定性。废水样品处理结果表明,Ni-TiO 光催化剂对 CF 和 TC 的去除率分别高达 88.6%和 80.2%。

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