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含胱氨酸的环氧基质实现的可回收碳纤维复合材料。

Recyclable carbon fibre composites enabled by cystine containing epoxy matrices.

作者信息

Henriksen Martin L, Friis Jakob E, Voss Astrid, Hinge Mogens

机构信息

Plastic and Polymer Engineering, Department of Engineering, Aarhus University Aabogade 40, 8200 Aarhus N Denmark

出版信息

RSC Adv. 2019 Oct 2;9(54):31378-31385. doi: 10.1039/c9ra06409e. eCollection 2019 Oct 1.

Abstract

Recyclable composites are of industrial relevance and benefits the environment, which initiates research towards more sustainable solutions. In this study, a commercial epoxy thermoset, modified by a bio-based additive is used as an infusion resin making recyclable carbon fibre composites. The matrix fractionation process was investigated and optimized with respect to additive & solvent concentration, and temperature. Fully cured carbon reinforced composites were dismantled under the optimum condition and after drying, reinfused, and cured into a new composite, repeated three times on the same carbon fibre material. A decrease in fibre volume fraction and composite performance was found as a number of recyclings were performed. Finally, it was demonstrated that the recycled carbon fibre ply could be reshaped, infused, and cured and thus be applied in new components.

摘要

可回收复合材料具有工业相关性且对环境有益,这引发了对更可持续解决方案的研究。在本研究中,一种由生物基添加剂改性的商用环氧热固性材料被用作灌注树脂来制造可回收碳纤维复合材料。针对添加剂和溶剂浓度以及温度,对基体分离过程进行了研究和优化。在最佳条件下将完全固化的碳增强复合材料拆解,干燥后重新灌注并固化成新的复合材料,在相同的碳纤维材料上重复此过程三次。随着回收次数的增加,发现纤维体积分数和复合材料性能有所下降。最后,证明了回收的碳纤维层可以重新成型、灌注和固化,从而应用于新部件。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d05/9072556/61d9668626dd/c9ra06409e-s1.jpg

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