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通过将生物环氧树脂复合材料转化为可重复使用的热塑性塑料回收用回收胺固化的热固性材料的创新化学工艺——生命周期评估研究

Innovative Chemical Process for Recycling Thermosets Cured with Recyclamines by Converting Bio-Epoxy Composites in Reusable Thermoplastic-An LCA Study.

作者信息

La Rosa Angela D, Blanco Ignazio, Banatao Diosdado R, Pastine Stefan J, Björklund Anna, Cicala Gianluca

机构信息

Department of Civil Engineering and Architecture and INSTM UdR, University of Catania, Viale A. Doria 6, 95125 Catania, Italy.

Connora Technologies Inc., 30621 San Antonio St, Hayward, CA 94544, USA.

出版信息

Materials (Basel). 2018 Feb 28;11(3):353. doi: 10.3390/ma11030353.

Abstract

An innovative recycling process for thermoset polymer composites developed by Connora Technologies (Hayward, CA, USA) was studied. The process efficacy has already been tested, and it is currently working at the plant level. The main aspect investigated in the present paper was the environmental impact by means of the Life Cycle Assessment (LCA) method. Because of the need to recycle and recover materials at their end of life, the Connora process creates a great innovation in the market of epoxy composites, as they are notoriously not recyclable. Connora Technologies developed a relatively gentle chemical recycling process that induces the conversion of thermosets into thermoplastics. The LCA demonstrated that low environmental burdens are associated with the process itself and, furthermore, impacts are avoided due to the recovery of the epoxy-composite constituents (fibres and matrix). A carbon fibre (CF) epoxy-composite panel was produced through Vacuum Resin Transfer Moulding (VRTM) and afterwards treated using the Connora recycling process. The LCA results of both the production and the recycling phases are reported.

摘要

对康诺拉技术公司(美国加利福尼亚州海沃德)开发的一种用于热固性聚合物复合材料的创新回收工艺进行了研究。该工艺的有效性已经过测试,目前正在工厂层面运行。本文研究的主要方面是通过生命周期评估(LCA)方法评估其环境影响。由于需要在材料使用寿命结束时进行回收和再利用,康诺拉工艺在环氧复合材料市场上带来了重大创新,因为环氧复合材料向来不可回收。康诺拉技术公司开发了一种相对温和的化学回收工艺,可促使热固性材料转化为热塑性材料。生命周期评估表明,该工艺本身的环境负担较低,此外,由于回收了环氧复合材料成分(纤维和基体),避免了一些影响。通过真空树脂传递模塑(VRTM)工艺生产了一种碳纤维(CF)环氧复合材料面板,然后使用康诺拉回收工艺进行处理。报告了生产阶段和回收阶段的生命周期评估结果。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8a5/5872932/2aeb4936df84/materials-11-00353-g001.jpg

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